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\n
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RTFIB\u306f\u3001\u30d5\u30ea\u30fc\u306eF\uff0d\u3042\u308b\u3044\u306fHF2\uff0d\u30a4\u30aa\u30f3\u3092\u78ba\u4fdd\u3057\u306a\u3051\u308c\u3070\u306a\u3089\u306a\u3044\u96e3\u3057\u3055\u304c\u3042\u308b(\u3059\u3050\u306bHF\u306b\u306a\u3063\u3066\u3057\u307e\u3046)\u3002\u30ab\u30bd\u30fc\u30c9\u3068\u3057\u3066BiF3\u3001\u30a2\u30ce\u30fc\u30c9\u306bLi\u3042\u308b\u3044\u306fMg\u3092\u7528\u3044\u3001\u96fb\u89e3\u8ceaNH4+HF2\uff0d\u3092PEG\u306b\u30c9\u30fc\u30d7NH4+PEG\u30ab\u30c1\u30aa\u30f3\u304c\u5f62\u6210\u3055\u308c\u3001HF2\uff0d\u304c\u96fb\u8377\u79fb\u52d5\u4f53\u3068\u306a\u308a\u3001PEG\u3068\u3057\u3066\u5206\u5b50\u91cf194\uff5e200,000\u3092\u691c\u8a0e\u3057\u3066\u3044\u308b\u3002\u5206\u5b50\u91cf\u304c\u4f4e\u3044\u65b9\u304c\u9ad8\u6027\u80fd\u3067\u3042\u3063\u305f\u3002250\u2103\u307e\u3067F\uff0d\u306f\u78ba\u4fdd\u3067\u304d\u305f\u3002\u30a4\u30aa\u30f3\u96fb\u5c0e\u5ea61000\u03bcS\/cm\u3068\u4f4e\u304f\u3001\u96fb\u6c17\u5316\u5b66\u7a93\u3082\u72ed\u304f\u3001\u30b5\u30a4\u30af\u30eb\u56de\u6570\u30820\u3002\u305d\u3053\u3067\u3001\u30ab\u30bd\u30fc\u30c9\u3068\u3057\u3066BiF3\u3001AlF3\u3001CuF2\u3001TiF3\u3000\u30a2\u30ce\u30fc\u30c9\u3068\u3057\u3066Li\u3001Mg\u3001Na\u3092\u9078\u5b9a\u3057\u3001\u305d\u306e\u7d44\u307f\u5408\u308f\u305b\u306e\u7814\u7a76\u304c\u884c\u308f\u308c\u3066\u3044\u308b\u30021)<\/p>\n 4\u3001\u8584\u819c\u96fb\u6975\u96fb\u89e3\u8cea Damien Dambournet\u3089\u306f\u3001\u56fa\u4f53\u72b6\u614b\u4e8c\u6b21FIB\u306b\u3064\u3044\u3066\u3001Bi\/BiF3\u96fb\u6975\u306e\u30b3\u30a4\u30f3\u30bb\u30eb\u3092\u4fee\u6b63\u3057\u3066\u3001\u30b0\u30ed\u30fc\u30d6\u30dc\u30c3\u30af\u30b9\u306e\u5916\u3067\u9ad8\u6e29\u4e0b\u9577\u6642\u9593\u306e\u96fb\u6c17\u5316\u5b66\u7684\u6027\u8cea\u3092\u8abf\u3079\u3066\u3044\u308b\u30024)150\u2103\u306b\u71b1\u3057\u305f\u30a8\u30dd\u30ad\u30b7\u6a39\u8102\u3067\u30b3\u30a4\u30f3\u30bb\u30eb\u3092\u8986\u3044\u3001\u7d50\u679c\u3068\u3057\u3066\u30bb\u30eb\u3092\u30b7\u30fc\u30eb\u3057\u305f\u3053\u3068\u306b\u306a\u3063\u305f\u30023\u30b5\u30a4\u30af\u30eb\u5f8c190mAh\/g\u306e\u5bb9\u91cf\u304c\u5f97\u3089\u308c\u305f\u3002<\/p>\n Xiangyang 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7)\u3001LiF\u3084NaF\u3092\u542b\u3080LiPF6\u3042\u308b\u3044\u306fLiBF4\u30c6\u30c8\u30e9\u30b0\u30e9\u30a4\u30e0\u6eb6\u6db2\u3042\u308b\u3044\u306f\u30c8\u30ea\u30b0\u30e9\u30a4\u30e0\u3068LiPF6\u3068\u306e\u30e2\u30eb\u6bd4\u304c8\u4ee5\u4e0b\u306e\u6eb6\u6db2(\u30e2\u30eb\u6bd4\u304c10\u4ee5\u4e0a\u306b\u306a\u308b\u3068Li\u30a4\u30aa\u30f3\u96fb\u6c60\u306b\u306a\u308b)8)\u3001\u30d5\u30c3\u5316\u7269\u932f\u30a2\u30cb\u30aa\u30f3\u3092\u542b\u3080\u30a4\u30aa\u30f3\u6db2\u4f53(N-\u30d6\u30c1\u30eb\u30d4\u30ea\u30cb\u30b8\u30a6\u30e0BF4)\u3068B(C6F5)3\u306e\u3088\u3046\u306a\u30a2\u30cb\u30aa\u30f3\u53d7\u5bb9\u4f53\u306e\u6eb6\u6db29)\u306a\u3069\u304c\u63d0\u6848\u3055\u308c\u3066\u3044\u308b\u3002<\/p>\n 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6\u3001\u304a\u308f\u308a\u306b \u6587\u732e<\/p>\n 1) F. Gschwind et al J. of Fluorine Chemistry 182(2016) 76 \u6700\u65b0\u30d5\u30c3\u7d20\u95a2\u9023\u30c8\u30d4\u30c3\u30af\u30b9\u300d\u306f\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u682a\u5f0f\u4f1a\u793e\u30d5\u30a1\u30a4\u30f3\u30b1\u30df\u30ab\u30eb\u90e8\u306e\u3054\u597d\u610f\u306b\u3088\u308a\u3001\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u306eWEB\u30de\u30ac\u30b8\u30f3\u306b\u63b2\u8f09\u3055\u308c\u305f\u5185\u5bb9\u3092\u7d39\u4ecb\u3057\u3066\u3044\u307e\u3059\u3002\u3054\u611b\u9867\u306e\u307b\u3069\u3088\u308d\u3057\u304f\u304a\u9858\u3044\u3044\u305f\u3057\u307e\u3059\u3002\u5c1a\u3001WEB\u30de\u30ac\u30b8\u30f3\u306eURL … \u7d9a\u304d\u3092\u8aad\u3080<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"class_list":["post-770","post","type-post","status-publish","format-standard","hentry","category-1"],"_links":{"self":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts\/770","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=770"}],"version-history":[{"count":2,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts\/770\/revisions"}],"predecessor-version":[{"id":777,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts\/770\/revisions\/777"}],"wp:attachment":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=770"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=770"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=770"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
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<\/a><\/p>\n
\nFIB\u306b\u306f\u3001\u5168\u56fa\u4f53FIB\uff08\u9ad8\u6e29FIB\u3001HTFIB\uff09\u3068\u6db2\u4f53\u96fb\u89e3\u8cea\u3067\u3001\u5ba4\u6e29\u3067\u4f5c\u52d5\u3059\u308bRTFIB\u304c\u3042\u308b\u3002<\/p>\n
\nMaximilian Fichtner\u3089\u306f\u3001\u4e0b\u56f3(a)\u306e\u30d0\u30eb\u30af\u578b\u96fb\u6c60\u3092\u4f5c\u88fd\u3002\u521d\u671f\u306f\u7406\u8ad6\u5024\u306e70%\u306e\u6027\u80fd\u304c\u9054\u6210\u3055\u308c\u3001\u5145\u653e\u96fb\u30b5\u30a4\u30af\u30eb\u306f700\u03bcm\u306e\u539a\u3044\u96fb\u89e3\u8cea\u5c64\u306e\u62b5\u6297\u304c\u5927\u304d\u304f\u3001\u307e\u305f\u96fb\u6975\u3068\u96fb\u89e3\u8cea\u9593\u306e\u63a5\u89e6\u304c\u4e0d\u5341\u5206\u306a\u305f\u3081\u62b5\u6297\u304c\u5897\u5927\u3057\u3001\u5bb9\u91cf\u4f4e\u4e0b\u304c\u5927\u304d\u304b\u3063\u305f\u3002\u305d\u3053\u3067(b\uff09\u306b\u793a\u3059\u8584\u819c\u96fb\u6975\u96fb\u89e3\u8cea\u3092\u63d0\u6848\u3002\u30be\u30eb\u30b2\u30eb\u30b9\u30d4\u30f3\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u3067\u5f97\u305f\u819c\u539a5\uff5e6\u03bcmLa0.9Ba0.1F2.9\u8584\u819c\u304c170\u2103\u30678.8\u00d710-5S\/cm\u306e\u96fb\u5c0e\u5ea6\u3092\u793a\u3057\u305f\u30022)
\n![\"\"](\"http:\/\/www.ft-net.co.jp\/topic\/wp-content\/uploads\/2017\/07\/ft03.gif\" "\\"ft03\\"")
<\/a>
\n\u307e\u305f\u3001La0.9Ba0.1F2.9\u6eb6\u6db2\u3092\u30b9\u30d4\u30f3\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u3001400\u3001450\u3001500\u2103\u30670.5\uff5e4\u6642\u9593\u30b7\u30f3\u30bf\u30ea\u30f3\u30b0\u3092\u884c\u3063\u305f\u3002\u305d\u306e\u4e2d\u3067450\u2103\u30014\u6642\u9593\u304b\u3051\u3066\u30b7\u30f3\u30bf\u30ea\u30f3\u30b0\u3057\u305f4\uff5e5\u03bcm\u306e\u8584\u819c\u306f170\u2103\u30671.6\u00d710-4S\/cm\u3067\u6700\u3082\u9ad8\u3044\u30a4\u30aa\u30f3\u4f1d\u5c0e\u5ea6\u3092\u793a\u3057\u305f\u30023)<\/p>\n
\n\u30ab\u30ea\u30d5\u30a9\u30eb\u30cb\u30a2\u30fb\u30a4\u30f3\u30b9\u30c6\u30a3\u30c6\u30e5\u30fc\u30c8\u30fb\u30aa\u30d6\u30c6\u30af\u30ce\u30ed\u30b8\u30fc\u306f\u30d5\u30eb\u30aa\u30e9\u30a4\u30c9\u30a4\u30aa\u30f3\u96fb\u6c60(FIB)\u3092\u691c\u8a0e\u3057\u3001LiB\u3068\u306e\u9055\u3044\u3092\u8868\u306b\u307e\u3068\u3081\u3066\u3044\u308b\u30026) FIB\u306e\u5229\u70b9\u306b\u306f\u3001\u30d5\u30c3\u5316\u7269\u30a4\u30aa\u30f3\u96fb\u6c17\u5316\u5b66\u30bb\u30eb\u306e\u5b89\u5168\u6027\u306e\u5411\u4e0a\u3001\u30d5\u30c3\u5316\u7269\u30a4\u30aa\u30f3\u96fb\u6c17\u5316\u5b66\u30bb\u30eb\u306e\u3088\u308a\u9ad8\u3044\u52d5\u4f5c\u96fb\u5727\u3001\u30d5\u30c3\u5316\u7269\u30a4\u30aa\u30f3\u96fb\u6c17\u5316\u5b66\u30bb\u30eb\u306b\u304a\u3051\u308b\u3088\u308a\u5927\u304d\u3044\u30a8\u30cd\u30eb\u30ae\u30fc\u5bc6\u5ea6\u3001\u53ca\u3073\u30d5\u30c3\u5316\u7269\u30a4\u30aa\u30f3\u96fb\u6c17\u5316\u5b66\u30bb\u30eb\u306e\u3088\u308a\u4f4e\u3044\u30b3\u30b9\u30c8\u3001\u304c\u542b\u307e\u308c\u308b\u3002
\n![\"\"](\"http:\/\/www.ft-net.co.jp\/topic\/wp-content\/uploads\/2017\/07\/ft04.gif\" "\\"ft04\\"")
<\/a>
\n\u30a2\u30cb\u30aa\u30f3\u53d7\u5bb9\u4f53\u3068\u3057\u3066\u3001B(OCH2CF3)3\u306a\u3069\u306e\u30db\u30a6\u7d20\u5316\u5408\u7269\u304c\u63d0\u6848\u3055\u308c\u3001\u30d5\u30eb\u30aa\u30e9\u30a4\u30c9\u30a4\u30aa\u30f3\u306e\u6eb6\u89e3\u5ea6\u3092\u9ad8\u3081\u308b\u306e\u306b\u5fc5\u9808\u3067\u3042\u308b\u3068\u3057\u3066\u3044\u308b\u3002\u5177\u4f53\u7684\u306b\u306fLa3-x\u3092\u8ca0\u6975\u306b\u3001CF\uff58\u3092\u6b63\u6975\u3068\u3059\u308b\u4f8b\u304c\u793a\u3055\u308c\u3066\u3044\u308b\u3002<\/p>\n
\n\u30d5\u30eb\u30aa\u30e9\u30a4\u30c9\u30a4\u30aa\u30f3\u96fb\u6c60\u306f\u7406\u8ad6\u7684\u306b\u306f\u73fe\u884c\u306e\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u3088\u308a\u6570\u500d\u306e\u306e\u5bb9\u91cf\u304c\u671f\u5f85\u3055\u308c\u308b\u304c\u3001\u30d7\u30ed\u30c8\u30f3\u3068\u306e\u53cd\u5fdc\u306b\u3088\u308aHF\u306b\u306a\u3063\u3066\u3057\u307e\u3046\u3053\u3068\u3001\u8584\u819c\u306b\u3057\u306a\u3044\u3068\u62b5\u6297\u304c\u5927\u304d\u304f\u7279\u306b\u5145\u653e\u96fb\u30b5\u30a4\u30af\u30eb\u7279\u6027\u304c\u4f4e\u3044\u3053\u3068\u306a\u3069\u307e\u3060\u307e\u3060\u5b9f\u7528\u5316\u306b\u306f\u304b\u306a\u308a\u9060\u3044\u611f\u3058\u304c\u3059\u308b\u3002\u4eac\u90fd\u5927\u5b66\u306f\u30c8\u30e8\u30bf\u81ea\u52d5\u8eca\u3084\u65e5\u7acb\u88fd\u4f5c\u6240\u306a\u3069\u3068\u5171\u540c\u3067\u672c\u96fb\u6c60\u306e\u5b9f\u7528\u5316\u306b\u5411\u3051\u3066\u5730\u9053\u306a\u52aa\u529b\u3092\u7d9a\u3051\u3066\u3044\u308b\u3002\u3053\u306e\u30dd\u30c6\u30f3\u30b7\u30e3\u30eb\u306e\u5927\u304d\u3055\u3092\u5b9f\u7528\u5316\u306b\u7d50\u3073\u4ed8\u3051\u308b\u3079\u304f\u3001\u96e3\u984c\u3092\u514b\u670d\u3057\u3066\u9032\u5316\u3057\u3066\u3044\u304f\u3053\u3068\u3092\u671f\u5f85\u3057\u305f\u3044\u3002<\/p>\n
\n2) Maximilian Fichtner et al Solid State Ionics 272(2015)39
\n3) Maximilian Fichtner et al J. of Alloys and Compounds 684(2016) 733-738
\n4) Damien Dambournet et al J. of Fluorine Chemistry 191(2016) 23-28
\n5) Xiangyang Zhou et al Electrochimica Acta 220(2016) 75-82
\n6) \u30ab\u30ea\u30d5\u30a9\u30eb\u30cb\u30a2\u30fb\u30a4\u30f3\u30b9\u30c6\u30a3\u30c6\u30e5\u30fc\u30c8\u30fb\u30aa\u30d6\u30c6\u30af\u30ce\u30ed\u30b8\u30fc\u3000\u7279\u958b2013-145758
\n7) \u30c8\u30e8\u30bf\u81ea\u52d5\u8eca\u3001\u4eac\u90fd\u5927\u5b66\u3000\u7279\u958b2016-062821
\n8) \u30c8\u30e8\u30bf\u81ea\u52d5\u8eca\u3001\u4eac\u90fd\u5927\u5b66\u3000\u7279\u958b2016-197543
\n9) \u30c8\u30e8\u30bf\u81ea\u52d5\u8eca\u3001\u4eac\u90fd\u5927\u5b66\u3000\u7279\u958b2016-164857
\n10) \u30c8\u30e8\u30bf\u81ea\u52d5\u8eca\u3001\u4eac\u90fd\u5927\u5b66\u3000\u7279\u958b2017-050113
\n11) \u30c8\u30e8\u30bf\u81ea\u52d5\u8eca\u3001\u4eac\u90fd\u5927\u5b66\u3000\u7279\u958b2017-054721
\n12) \u65e5\u7acb\u88fd\u4f5c\u6240\u3001\u4eac\u90fd\u5927\u5b66\u3000\u7279\u958b2017-10865
\n13) \u672c\u7530\u6280\u7814\u5de5\u696d\u3001\u4eac\u90fd\u5927\u5b66\u3000\u7279\u958b2017-88427<\/p>\n","protected":false},"excerpt":{"rendered":"