{"id":626,"date":"2014-03-06T09:52:32","date_gmt":"2014-03-06T00:52:32","guid":{"rendered":"http:\/\/ft-net.co.jp\/topic\/?p=626"},"modified":"2014-03-06T09:52:32","modified_gmt":"2014-03-06T00:52:32","slug":"%e3%80%8c%e3%83%8a%e3%83%88%e3%83%aa%e3%82%a6%e3%83%a0%e3%82%a4%e3%82%aa%e3%83%b3%e9%9b%bb%e6%b1%a0%e3%80%8d","status":"publish","type":"post","link":"https:\/\/ft-net.co.jp\/topic\/?p=626","title":{"rendered":"\u300c\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u300d"},"content":{"rendered":"

\u6700\u65b0\u30d5\u30c3\u7d20\u95a2\u9023\u30c8\u30d4\u30c3\u30af\u30b9\u300d\u306f\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u682a\u5f0f\u4f1a\u793e\u30d5\u30a1\u30a4\u30f3\u30b1\u30df\u30ab\u30eb\u90e8\u306e\u3054\u597d\u610f\u306b\u3088\u308a\u3001\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u306eWEB\u30de\u30ac\u30b8\u30f3\u306b\u63b2\u8f09\u3055\u308c\u305f\u5185\u5bb9\u3092\u7d39\u4ecb\u3057\u3066\u3044\u307e\u3059\u3002\u3054\u611b\u9867\u306e\u307b\u3069\u3088\u308d\u3057\u304f\u304a\u9858\u3044\u3044\u305f\u3057\u307e\u3059\u3002\u5c1a\u3001WEB\u30de\u30ac\u30b8\u30f3\u306eURL\u306f\u4e0b\u8a18\u306e\u901a\u308a\u3067\u3059\u3002
\nhttp:\/\/www.daikin.co.jp\/chm\/products\/fine\/backnum\/201403\/<\/p>\n

1\u3001\u306f\u3058\u3081\u306b
\n \u30ea\u30c1\u30a6\u30e0\u4e8c\u6b21\u96fb\u6c60\u306f\u3001\u4eca\u3084\u65b0\u30a8\u30cd\u30eb\u30ae\u30fc\u3068\u3057\u3066\u5bb6\u96fb\u7528\u3067\u306f\u6700\u3082\u4f7f\u308f\u308c\u3001\u8eca\u8f09\u7528\u3068\u3057\u3066\u3082\u4eca\u5f8c\u306e\u671f\u5f85\u304c\u5927\u304d\u3044\u3002\u3057\u304b\u3057\u3001\u539f\u6599\u554f\u984c\u3001\u5b89\u5168\u6027\u306e\u554f\u984c\u306a\u3069\u8ab2\u984c\u306f\u591a\u3044\u3002\u305d\u3053\u3067\u3001\u305d\u306e\u554f\u984c\u3092\u89e3\u6c7a\u3057\u3001\u30b3\u30b9\u30c8\u7684\u306b\u3082\u512a\u4f4d\u306a\u30ca\u30c8\u30ea\u30a6\u30e0\u96fb\u6c60\u306e\u958b\u767a\u304c\u9032\u3093\u3067\u3044\u308b\u3002\u672c\u7a3f\u3067\u306f\u6700\u8fd1\u306e\u6587\u732e\u3001\u7279\u8a31\u304b\u3089\u305d\u306e\u52d5\u5411\u304a\u3088\u3073\u305d\u306e\u4e2d\u3067\u306e\u30d5\u30c3\u7d20\u304c\u3069\u306e\u3088\u3046\u306b\u4f7f\u7528\u3055\u308c\u3066\u3044\u308b\u306e\u304b\u3092\u63a2\u3063\u3066\u307f\u305f\u3002 <\/p>\n

2\u3001\u30ca\u30c8\u30ea\u30a6\u30e0\u96fb\u6c60\u306e\u6982\u8981
\n\u30ca\u30c8\u30ea\u30a6\u30e0\u96fb\u6c60\u306e\u69cb\u9020\u306f\u4e0b\u8a18\u306e\u901a\u308a\u3067\u3042\u308a\u3001\u57fa\u672c\u7684\u306b\u306f\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u3092\u30ca\u30c8\u30ea\u30a6\u30e0\u306b\u7f6e\u304d\u63db\u3048\u305f\u69cb\u9020\u3092\u3057\u3066\u3044\u308b\u30021)\u4f46\u3057\u3001\u30ca\u30c8\u30ea\u30a6\u30e0\u306f\u30ea\u30c1\u30a6\u30e0\u306b\u5bfe\u3057\u3001\u30a4\u30aa\u30f3\u4f53\u7a4d\u306b\u3057\u30662\u500d\u9ad8\u304f\u3001\u539f\u5b50\u91cf\u306b\u3057\u30663\u500d\u4ee5\u4e0a\u5927\u304d\u3044\u306e\u3067\u3001\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u3067\u7528\u3044\u3089\u308c\u3066\u3044\u308b\u8ca0\u6975\u6750\u6599\u9ed2\u925b\u3067\u306f\u3001\u5438\u8535\u653e\u51fa\u3055\u305b\u308b\u3053\u3068\u304c\u4e0d\u53ef\u80fd\u3067\u3042\u308b\u3002\u5f93\u3063\u3066\u3001\u8ca0\u6975\u6750\u6599\u3068\u3057\u3066\u30cf\u30fc\u30c9\u30ab\u30fc\u30dc\u30f3\u3092\u7528\u3044\u308b\u306a\u3069\u3001\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u7528\u306b\u6b63\u6975\u3082\u542b\u3081\u3066\u958b\u767a\u304c\u5fc5\u8981\u3067\u3042\u3063\u305f\u30022)
\n\"FT1\"<\/p>\n

3\u3001\u30ca\u30c8\u30ea\u30a6\u30e0\u96fb\u6c60\u306b\u304a\u3051\u308b\u30d5\u30c3\u7d20
\n\u30ca\u30c8\u30ea\u30a6\u30e0\u96fb\u6c60\u306b\u304a\u3044\u3066\u3001\u30d5\u30c3\u7d20\u304c\u4f7f\u308f\u308c\u3066\u3044\u308b\u3042\u308b\u3044\u306f\u63d0\u6848\u3055\u308c\u3066\u3044\u308b\u306e\u306f\u96fb\u89e3\u6db2\u3068\u96fb\u6975\u3067\u3042\u308b\u3002\u305d\u308c\u305e\u308c\u306b\u3064\u3044\u3066\u8ff0\u3079\u3066\u3044\u304f\u3002<\/p>\n

3-1\u3001\u96fb\u89e3\u6db2
\n\u30cf\u30fc\u30c9\u30ab\u30fc\u30dc\u30f3\u306f\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u3092\u53ef\u9006\u7684\u306b\u8131\u633f\u5165\u53ef\u80fd\u3067\u306f\u3042\u308b\u304c\u3001\u30b5\u30a4\u30af\u30eb\u5b89\u5b9a\u6027\u304c\u4e0d\u5341\u5206\u3067\u3042\u308b\u3068\u3044\u3046\u8ab2\u984c\u304c\u3042\u3063\u305f\u3002\u3057\u304b\u3057\u3001\u99d2\u5834\u3089\u306f\u96fb\u89e3\u6db2\u3068\u3057\u3066\u3001\u30a8\u30c1\u30ec\u30f3\u30ab\u30fc\u30dc\u30cd\u30fc\u30c8(EC)\u3084\u30d7\u30ed\u30d4\u30ec\u30f3\u30ab\u30fc\u30dc\u30cd\u30fc\u30c8(PC)\u3092\u5358\u72ec\u3042\u308b\u3044\u306f1\uff1a1\u6df7\u5408\u6eb6\u5a92\u3067\u7528\u3044\u308b\u3068\u826f\u597d\u306a\u30b5\u30a4\u30af\u30eb\u7279\u6027\u304c\u5f97\u3089\u308c\u308b\u3053\u3068\u3092\u898b\u51fa\u3057\u305f\u30023)\u30b8\u30e1\u30c1\u30eb\u30ab\u30fc\u30dc\u30cd\u30fc\u30c8\u3092\u4f7f\u7528\u3057\u305f\u5834\u5408\u3001\u30ca\u30c8\u30ea\u30a6\u30e0\u30a2\u30eb\u30b3\u30ad\u30b7\u30c9\u306a\u3069\u306e\u96fb\u89e3\u6db2\u5206\u89e3\u7269\u304c\u591a\u91cf\u306b\u767a\u751f\u3057\u3066\u30b5\u30a4\u30af\u30eb\u7279\u6027\u3092\u4f4e\u4e0b\u3055\u305b\u3066\u3044\u308b\u3053\u3068\u304c\u5206\u304b\u3063\u305f\u3002\u30ea\u30c1\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306b\u304a\u3044\u3066\u306f\u3001\u8ca0\u6975\u4e0a\u306b\u4e0d\u52d5\u614b\u88ab\u819c(SEI)\u3092\u5f62\u6210\u3055\u305b\u308b\u3079\u304f\u6dfb\u52a0\u5264\u3092\u4f7f\u7528\u3057\u3066\u3044\u308b\u304c\u3001\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306b\u304a\u3044\u3066\u3082\u540c\u3058\u624b\u6bb5\u304c\u6709\u52b9\u3067\u3042\u308b\u3053\u3068\u304c\u5206\u304b\u3063\u305f\u3002<\/p>\n

\u8429\u539f\u3089\u306f\u3001423K\u3067\u4f5c\u7528\u3059\u308bNaCrO2\u3092\u6b63\u6975\u3068\u3059\u308b\u30ca\u30c8\u30ea\u30a6\u30e0\u4e8c\u6b21\u96fb\u6c60\u306b\u304a\u3051\u308b\u65b0\u96fb\u89e3\u8cea\u3068\u3057\u3066\u3001\u30a4\u30aa\u30f3\u6db2\u4f53NaTFSA(10mol%)\/CsTFSA(90mol%)\u3092\u691c\u8a0e\u3057\u305f\u30024)\u3053\u306e\u30a4\u30aa\u30f3\u6db2\u4f53\u306e423K\u3067\u306e\u7c98\u5ea6\u3001\u30a4\u30aa\u30f3\u4f1d\u5c0e\u5ea6\u3001\u5bc6\u5ea6\u3001\u96fb\u6c17\u5316\u5b66\u7a93\u306f\u305d\u308c\u305e\u308c\u300142.5cp\u300112.1mS\/cm\u30012.29g\/cm-3\u30014.9V\u3067\u3042\u3063\u305f\u3002\u672c\u6761\u4ef6\u3067\u306e\u5145\u653e\u96fb\u7279\u6027\u3092\u8abf\u3079\u3001\u5b9a\u96fb\u6d41\u901f\u5ea6\u304c10\u30b5\u30a4\u30af\u30eb\u5f8c10mA\/g\u306e\u5834\u5408\u306850\u30b5\u30a4\u30af\u30eb\u5f8c100mA\/g\u306e\u5834\u5408\u306b\u304a\u3051\u308b\u653e\u96fb\u5bb9\u91cf\u306f\u305d\u308c\u305e\u308c83.0mAh\/g\u300166.4mAh\/g\u3067\u3042\u3063\u305f\u3002\u521d\u671f\u306e\u6570\u30b5\u30a4\u30af\u30eb\u3092\u9664\u304f\u3068\u30af\u30fc\u30ed\u30f3\u52b9\u7387\u306f99.5%\u4ee5\u4e0a\u3067\u3042\u3063\u305f\u3002\u3053\u306e\u3053\u3068\u304b\u3089\u3001\u3053\u306e\u30ca\u30c8\u30ea\u30a6\u30e0\u4e8c\u6b21\u96fb\u6c60\u304c423K\u3092\u4e2d\u5fc3\u3068\u3059\u308b373K\u304b\u3089473K\u306e\u6e29\u5ea6\u7bc4\u56f2\u3067\u65b0\u898f\u4e8c\u6b21\u96fb\u6c60\u3068\u3057\u3066\u6709\u671b\u3067\u3042\u308b\u3068\u3057\u3066\u3044\u308b\u3002<\/p>\n

3-2\u3000\u96fb\u6975
\n\u5ca1\u7530\u3089\u306f\u3001Na3M2(PO4)2F3[M=Ti, Fe, V]\u30922\u6bb5\u968e\u56fa\u4f53\u72b6\u614b\u5408\u6210\u3067\u5408\u6210\u3057\u3001\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u8ca0\u6975\u6d3b\u7269\u8cea\u3068\u3057\u3066\u306e\u53ef\u80fd\u6027\u3092\u8abf\u3079\u305f\u30025)\u5408\u6210\u306f\u3001V2O5\u3042\u308b\u3044\u306fTi2O3\u3068\uff08NH4)2HPO4\u3068\u3092\u6df7\u5408\u3057\u3001650\uff5e950\u210315\u6642\u9593\u71b1\u3059\u308b\u304b\u3001FePO4\u30fb2H2O\u3092100\u2103\u3001\u771f\u7a7a\u4e2d\u30673\u6642\u9593\u71b1\u3057\u3066MPO4\u306e\u5f62\u306b\u3057\u3001\u6b21\u3044\u3067\u3001NaF\u3068\u6df7\u5408\u3057\u3066\u7a7a\u6c17\u6d41\u306e\u4e2d\u3067600\u21032\u6642\u9593\u53cd\u5fdc\u3055\u305b\u305f\u3002Na3V2(PO4)2F3\u306e\u5834\u5408\u3001\u69cb\u9020\u306f\u4e0b\u56f3\u306e\u5f62\u3067\u3042\u308b\u3053\u3068\u304cX\u7dda\u89e3\u6790\u304b\u3089\u63a8\u5b9a\u3055\u308c\u305f\u3002\u305d\u3057\u3066\u3001Na3V2(PO4)2F3\u304c\u5bb9\u91cf\u3068\u3057\u3066120mA\u3067\u3042\u308a\u3001\u30b5\u30a4\u30af\u30eb\u7279\u6027\u308220\u30b5\u30a4\u30af\u30eb\u5f8c\u306e\u4fdd\u6301\u7387\u304c98%\u3068\u9ad8\u304f\u3001\u5b89\u5b9a\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u3063\u305f\u3002\u307e\u305f\u3001\u9078\u5b9a\u96fb\u5727\u3067\u5145\u653e\u96fb\u3057\u305f\u6642\u306eNa3V2(PO4)2F3\u96fb\u6975\u306eex-situ XRD\u6e2c\u5b9a\u30c7\u30fc\u30bf\u304b\u3089\u3001\u7269\u8cea\u69cb\u9020\u306fc\u8ef8\u306b\u6cbf\u3063\u30664.3V\u307e\u3067\u81a8\u5f35\u3057\u3001\u30b5\u30a4\u30af\u30eb\u5f8c\u306f\u5143\u306e\u5927\u304d\u3055\u306b\u3082\u3069\u308b\u3053\u3068\u304c\u5206\u304b\u3063\u305f\u3002\u3053\u306e\u3053\u3068\u306f\u3001Na\u539f\u5b50\u304c\u6b63\u65b9\u6676\u69cb\u9020\u306e\u4e2d\u3067\uff08002\uff09a-b\u9762\u306b\u6cbf\u3063\u3066\u51fa\u5165\u308a\u3057\u3066\u3044\u308b\u3053\u3068\u306b\u3088\u308b\u3068\u3057\u3066\u3044\u308b\u3002
\n\"FT2\"
\nTeofilo Rojo\u3089\u306f\u3001\u6df7\u5408\u539f\u5b50\u4fa1\u30ca\u30c8\u30ea\u30a6\u30e0-\u30d0\u30ca\u30b8\u30a6\u30e0\u30d5\u30c3\u5316\u30ea\u30f3\u9178Na3V2Ox(PO4)2F3-x(0\uff1c\uff58\uff1c\uff11)\u3068\u30ab\u30fc\u30dc\u30f3\u304b\u3089\u6210\u308b\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u3092\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u6b63\u6975\u306b\u4f7f\u7528\u3057\u3066\u305d\u306e\u53ef\u80fd\u6027\u3092\u8abf\u3079\u3066\u3044\u308b\u3002\uff58\u304c0\u306e\u6642\u306fV3+\u3067\u3042\u308a(Na3V2(PO4)2F3)\u3001\uff58\u304c1\u306e\u6642\u306fV4+\u3068\u306a\u308a(Na3(VO)2(PO4)2)\u3001\u3053\u306e\u539f\u5b50\u4fa1\u306e\u5909\u5316\u306f\u30ab\u30fc\u30dc\u30f3\u306e\u5f71\u97ff\u3092\u53d7\u3051\u3066\u3044\u308b\u30026)\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u306e\u56fa\u6709\u9762\u7a4d\u306f67m2\/g\u3068\u9ad8\u304f\u3001\u56fa\u6709\u306e\u5145\u653e\u96fb\u5bb9\u91cf\u306e\u30b5\u30a4\u30af\u30eb\u7279\u6027\u306f\u4e0b\u56f3\u306e\u901a\u308a\u3067\u30011C\u3001200\u30b5\u30a4\u30af\u30eb\u306799%\u4ee5\u4e0a\u306e\u30af\u30fc\u30ed\u30f3\u52b9\u7387\u304c\u5f97\u3089\u308c\u3001\u30ca\u30c8\u30ea\u30a6\u30e0\u30a4\u30aa\u30f3\u96fb\u6c60\u306e\u6b63\u6975\u3068\u3057\u3066\u512a\u308c\u305f\u7279\u6027\u3092\u6709\u3057\u3066\u3044\u308b\u3068\u3057\u3066\u3044\u308b\u3002
\n\"FT3\"<\/p>\n

4\u3001\u304a\u308f\u308a\u306b
\n\u6700\u8fd1\u306e\u7279\u8a31\u3092\u898b\u308b\u3068\u3001\u30c8\u30e8\u30bf\u81ea\u52d5\u8eca\u304c\u96fb\u89e3\u8cea\u3068\u3057\u3066NaPF6\u3092\u7528\u3044\u3001\u8ca0\u6975\u306b\u70ad\u7d20\u6750\u6599\u3001\u5bfe\u6975\u306b\u91d1\u5c5eNa\u3092\u7528\u3044\u305f\u30ca\u30c8\u30ea\u30a6\u30e0\u4e8c\u6b21\u96fb\u6c60\u3092\u63d0\u6848\u3057\u3066\u3044\u308b\u30027)\u307e\u305f\u3001\u672c\u7530\u6280\u7814\u5de5\u696d\u3082\u96fb\u89e3\u8cea\u3068\u3057\u3066NaPF6\u3001\u6b63\u6975\u306b\u30b0\u30e9\u30d5\u30a1\u30a4\u30c8\u3001\u5bfe\u6975\u306b\u91d1\u5c5eNa\u3092\u7528\u3044\u305f\u30ca\u30c8\u30ea\u30a6\u30e0\u4e8c\u6b21\u96fb\u6c60\u3092\u63d0\u6848\u3057\u3066\u3044\u3066\u30018)\u5b9f\u7528\u5316\u306b\u5411\u3051\u958b\u767a\u304c\u9032\u3093\u3067\u3044\u308b\u69d8\u5b50\u304c\u3046\u304b\u304c\u308f\u308c\u308b\u3002\u4eca\u5f8c\u306e\u52d5\u304d\u306b\u6ce8\u76ee\u3057\u305f\u3044\u3002<\/p>\n

\u6587\u732e
\n1) \u99d2\u5834\u614e\u4e00
\nhttp:\/\/j-net21.smrj.go.jp\/develop\/energy\/company\/2012121301.html
\n 2) \u4f4f\u53cb\u5316\u5b66\u7b51\u6ce2\u958b\u767a\u7814\u7a76\u6240\u3000\u4f4f\u53cb\u5316\u5b662013\u3000p20-30
\n 3) \u99d2\u5834\u614e\u4e00\u4ed6\u3001\u30d5\u30a1\u30a4\u30f3\u30b1\u30df\u30ab\u30eb2012\u5e748\u6708\u53f7\u3000p22-28
\n 4) Rika Hagiwara et al \u3000Journal of Power Sources 205(2012) 506-509
\n 5) Shigeto Okada et al \u3000Journal of Power Sources 227(2013) 80-85
\n 6) Teofilo Rojo et al Journal of Power Sources 241(2013) 56-60
\n 7) \u30c8\u30e8\u30bf\u81ea\u52d5\u8eca\u3000\u7279\u958b2013-137907
\n 8) \u672c\u7530\u6280\u7814\u5de5\u696d\u3000\u7279\u958b2013-54987<\/p>\n","protected":false},"excerpt":{"rendered":"

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