{"id":606,"date":"2013-12-03T16:31:51","date_gmt":"2013-12-03T07:31:51","guid":{"rendered":"http:\/\/ft-net.co.jp\/topic\/?p=606"},"modified":"2013-12-03T16:31:51","modified_gmt":"2013-12-03T07:31:51","slug":"%e3%80%8c%e3%83%95%e3%83%83%e7%b4%a0%e5%8c%96%e5%90%88%e7%89%a9%e3%81%ae%e7%ab%8b%e4%bd%93%e9%81%b8%e6%8a%9e%e7%9a%84%e5%90%88%e6%88%90%e3%80%8d","status":"publish","type":"post","link":"https:\/\/ft-net.co.jp\/topic\/?p=606","title":{"rendered":"\u300c\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u7acb\u4f53\u9078\u629e\u7684\u5408\u6210\u300d"},"content":{"rendered":"

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\nhttp:\/\/www.daikin.co.jp\/chm\/products\/fine\/backnum\/201312\/<\/p>\n

1\u3001\u306f\u3058\u3081\u306b
\n \u30d5\u30c3\u7d20\u306e\u9ad8\u96fb\u6c17\u9670\u6027\u5ea6\u3001\u8102\u6eb6\u6027\u3001\u30df\u30df\u30c3\u30af\u52b9\u679c\u306a\u3069\u306e\u7279\u5fb4\u3092\u6d3b\u304b\u3057\u305f\u30d5\u30c3\u7d20\u7cfb\u533b\u85ac\u30fb\u8fb2\u85ac\u304c\u307e\u3059\u307e\u3059\u91cd\u8981\u6027\u3092\u5897\u3057\u3066\u3044\u308b\u3002\u7279\u306b\u7acb\u4f53\u9078\u629e\u6027\u3092\u6709\u3059\u308b\u30d5\u30c3\u7d20\u5316\u5408\u7269\u304c\u7279\u7570\u306a\u751f\u7406\u6d3b\u6027\u3084\u96fb\u5b50\u7684\u7279\u6027\u3092\u767a\u63ee\u3057\u3066\u65b0\u305f\u306a\u6750\u6599\u3068\u3057\u3066\u6ce8\u76ee\u3055\u308c\u3066\u3044\u308b\u3002\u3053\u3053\u3067\u306f\u6700\u8fd1\u306e\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u7acb\u4f53\u9078\u629e\u7684\u5408\u6210\u6cd5\u306b\u3064\u3044\u3066\u3001\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u30d5\u30c3\u7d20\u5316\u3068\u3001\u542b\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u7acb\u4f53\u9078\u629e\u7684\u53cd\u5fdc\u306b\u3064\u3044\u3066\u306e\u6587\u732e\u3092\u7d39\u4ecb\u3059\u308b\u3002 <\/p>\n

2\u3001\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u30d5\u30c3\u7d20\u5316
\nXian Jin Young\u3089\u306f\u3001\u4e0b\u56f3\u306eN-\u30d5\u30eb\u30aa\u30ed\u30d9\u30f3\u30bc\u30f3\u30b9\u30eb\u30db\u30f3\u30a2\u30df\u30c9\u3092\u7528\u3044\u3066\u30aa\u30ad\u30b7\u30a4\u30f3\u30c9\u30fc\u30eb2a\u306e\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u5408\u6210\u3092\u884c\u3063\u305f\u30021)\u305d\u306e\u7d50\u679c\u3001\u4e0b\u8868\u306b\u793a\u3059\u3088\u3046\u306b\u30d1\u30e9\u4f4d\u306eR\u304cH\u3084F\u306e\u6642\u306b\u9ad8\u3044\u53ce\u7387\u304c\u5f97\u3089\u308c\u3001\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u6027\u308270\u4ee5\u4e0a\u3067\u3042\u3063\u305f\u3002
\n\"FT1\"
\nFedor Zhuravlev\u3089\u306f\u3001\u4e0b\u56f3\u306e\u30a8\u30dd\u30ad\u30b7\u5316\u5408\u7269\u3092\u30ac\u30b9\u72b6\u306e[18F]HF\u30672\u306e\u30b3\u30d0\u30eb\u30c8\u932f\u4f53\u3092\u89e6\u5a92\u3068\u3057\u3066\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u653e\u5c04\u6027\u30d5\u30c3\u7d20\u5316\u3092\u884c\u3063\u305f\u30022)\u305d\u306e\u7d50\u679c\u3001R\u2019OH\u3068\u3057\u3066(CF3)2CHOH\u3001\u6eb6\u5a92\u3068\u3057\u3066tert-\u30a2\u30df\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u3001\u5869\u57fa\u3068\u3057\u3066\u30c6\u30c8\u30e9\u30a2\u30df\u30bd\u30fc\u30eb\u3001\u89e6\u5a92\u3068\u3057\u3066(R,R)-Co(salen)\u3092\u7528\u3044\u305f\u5834\u5408\u3001\u653e\u5c04\u5316\u5b66\u53ce\u7387(RCY)50%\u3001\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u6027(ee)68%\u3092\u5f97\u305f\u3002\u307e\u305f\u3001\u4ed6\u306e\u6761\u4ef6\u306f\u540c\u3058\u3067\u6eb6\u5a92\u3068\u3057\u3066tert-\u30d6\u30c1\u30eb\u30e1\u30c1\u30eb\u30a8\u30fc\u30c6\u30eb\u3092\u7528\u3044\u305f\u5834\u5408\u306fRCY\u304c78%\u3001ee\u304c32%\u3067\u3042\u3063\u305f\u3002 R\u2019OH\u3068\u3057\u3066\u975e\u30d5\u30c3\u7d20\u7cfb\u306e\u30a2\u30eb\u30b3\u30fc\u30eb\u3092\u7528\u3044\u305f\u5834\u5408\u306f\u3001\u307b\u3068\u3093\u3069\u53cd\u5fdc\u304c\u9032\u307e\u306a\u304b\u3063\u305f\u3002\u3053\u308c\u306f\u30d5\u30eb\u30aa\u30e9\u30b9\u52b9\u679c\u3060\u3068\u3057\u3066\u3044\u308b\u3002
\n\"FT2\"
\nDae Young Kim\u3089\u306f\u3001\u4e0b\u56f3\u306e\u89e6\u5a92(cat.1)\u3092\u7528\u3044\u3066\u3001\u4e0b\u5f0f\u306e\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u5408\u6210\u3092\u884c\u3063\u305f\u30023)\u305d\u306e\u7d50\u679c\u30011f\u306eAr\u3068\u3057\u3066m-\u30ad\u30b7\u30ec\u30f3\u3001X\u304cOTf\u306e\u6642\u3001\u6700\u3082\u9ad8\u3044\u53ce\u7387\u3068ee\u3092\u5f97\u305f\u3002\u3055\u3089\u306b\u30012,6-Di-tert-butyl-4-methylpyridine\u3092\u6dfb\u52a0\u3059\u308b\u3068\u53ce\u738790%\u3001ee91%\u3092\u5f97\u3066\u3044\u308b\u3002
\n\"FT3\"
\n3\u3001\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u7acb\u4f53\u9078\u629e\u7684\u53cd\u5fdc
\n\u4ed9\u5317\u3089\u306f\u3001\u4e0b\u56f3\u306b\u793a\u3059\u30da\u30f3\u30bf\u30d5\u30eb\u30aa\u30ed\u30d9\u30f3\u30bc\u30f3\u8a98\u5c0e\u4f53\u306e\u7acb\u4f53\u9078\u629e\u7684\u96fb\u6c17\u5316\u5b66\u7684\u30ab\u30eb\u30dc\u30ad\u30b7\u30eb\u5316\u53cd\u5fdc\u3092\u5831\u544a\u3057\u3066\u3044\u308b\u30024)Pt\u8ca0\u6975\u3001Mg\u6b63\u6975\u306b\u3088\u308b\u96fb\u89e3\u30ab\u30eb\u30dc\u30ad\u30b7\u30eb\u5316\u3067\u3001\u6eb6\u5a92\u306fDMF\u3001\u53cd\u5fdc\u6e29\u5ea6\u201040\u2103\u3001\u96fb\u6d41\u5bc6\u5ea6\u306f5mA\/cm2\u3067\u3001C3\u4f4d\u304c\u9ad8\u3044\u9078\u629e\u6027\u3067\u30ab\u30eb\u30dc\u30ad\u30b7\u30eb\u5316\u3055\u308c\u305f\u3002
\n\"FT4\"
\n\u4f0a\u85e4\u3089\u306f\u3001\u30d1\u30e9\u30b8\u30a6\u30e0\u89e6\u5a92\u3092\u7528\u3044\u3066CF3\u57fa\u542b\u6709\u30a2\u30ea\u30eb\u30a2\u30df\u30f3\u306e\u7acb\u4f53\u9078\u629e\u7684\u5408\u6210\u3092\u5831\u544a\u3057\u3066\u3044\u308b\u30025)\u4e0b\u56f3\u306e1a\u304b\u3089\u03b3\u751f\u6210\u72692a\u3001\u3042\u308b\u3044\u306f\u03b1\u751f\u6210\u72693a\u3092\u5408\u6210\u3059\u308b\u5834\u5408\u3001\u4e0b\u8868\u306b\u793a\u3059\u3088\u3046\u306bA\u306ePd(OAc)2\u3067DPPE\u3092\u914d\u4f4d\u5b50\u3068\u3057\u305f\u89e6\u5a92\u7cfb\u304c\u9ad8\u3044\u6d3b\u6027\u3068\u03b3\u751f\u6210\u7269\u3078\u306e\u9ad8\u3044\u9078\u629e\u6027\u3092\u793a\u3057\u305f\u3002\u307e\u305f\u3001[Pd(\u03c0-allyl)(cod)]BF4\/DPPF\u932f\u4f53\u89e6\u5a92\u3092\u7528\u3044\u305f\u5834\u5408\u306f\u3001\u03b3\u751f\u6210\u7269\u304c\u5bb9\u6613\u306b\u03b1\u751f\u6210\u7269\u3078\u8ee2\u5316\u3057\u305f\u3002
\n\"FT5\"
\nNiloZanatta\u3089\u306f\u3001\u4e0b\u56f3\u306b4-\u30a2\u30eb\u30b3\u30ad\u30b7-1,1,1\u30c8\u30ea\u30d5\u30eb\u30aa\u30ed-3-\u30a2\u30eb\u30b1\u30f3-2-\u30aa\u30f3(R\u306fEt\u3042\u308b\u3044\u306fMe)\u304b\u3089\u3001CF3\u57fa\u542b\u6709\u306e\u30d4\u30e9\u30be\u30fc\u30eb1,3-\u3042\u308b\u3044\u306f1,5-\u7570\u6027\u4f53\u306e\u7acb\u4f53\u9078\u629e\u7684\u5408\u6210\u306b\u3064\u3044\u3066\u5831\u544a\u3057\u3066\u3044\u308b\u30026)
\n\"FT6\"
\n\u305d\u306e\u7d50\u679c\u3001\u30d5\u30a7\u30cb\u30eb\u30d2\u30c9\u30e9\u30b8\u30f3\u3068\u306e\u4e00\u6bb5\u5408\u6210\u3067\u306f1,5-Isomer\u304c\u9078\u629e\u7684\u306b\u5408\u6210\u3055\u308c\u30011,3-Isomer\u306b\u3064\u3044\u3066\u306f9-15\u306e\u30a8\u30ca\u30df\u30ce\u30f3\u3092\u7d4c\u3066\u9078\u629e\u7684\u306b\u5408\u6210\u3067\u304d\u305f\u3002<\/p>\n

4\u3001\u304a\u308f\u308a\u306b
\n\u7acb\u4f53\u9078\u629e\u7684\u306a\u542b\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u5408\u6210\u306b\u3064\u3044\u3066\u3001\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\u30d5\u30c3\u7d20\u5316\u3068\u542b\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u7acb\u4f53\u9078\u629e\u7684\u5408\u6210\u306b\u3064\u3044\u3066\u306e\u6700\u65b0\u306e\u6587\u732e\u3092\u7d39\u4ecb\u3057\u305f\u3002\u305d\u306e\u80cc\u666f\u306b\u306f\u533b\u85ac\u30fb\u8fb2\u85ac\u30fb\u96fb\u5b50\u6750\u6599\u304b\u3089\u306e\u5f37\u3044\u8981\u6c42\u304c\u3042\u308b\u3053\u3068\u304c\u4f3a\u308f\u308c\u3001\u7279\u8a31\u7684\u306b\u3082\u533b\u85ac\u30e1\u30fc\u30ab\u30fc\u304b\u3089\u306e\u3082\u306e\u304c\u76ee\u7acb\u3064\u3002\u4eca\u5f8c\u3082\u3053\u306e\u5206\u91ce\u306b\u6ce8\u76ee\u3057\u3066\u3044\u304d\u305f\u3044\u3002<\/p>\n

\u6587\u732e
\n1) Xian Jin Young et al Tetrahedron 69(2013) 4933-4937
\n 2) Fedor Zhuravlev Journal of Fluorine Chemistry 156(2013) 130-135
\n 3) Dae Young Kim Tetrahedron Letters 54(2013) 3359-3362
\n 4) HisanoriSenboku et al Electrochemistry 81(2013) 380-382
\n 5) Toshiyuki Itoh et al Journal of Fluorine Chemistry 152(2013) 62-69
\n 6) NiloZanatta et al Tetrahedron Letters 54(2013)4076-4079<\/p>\n","protected":false},"excerpt":{"rendered":"

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