{"id":542,"date":"2013-10-15T15:56:18","date_gmt":"2013-10-15T06:56:18","guid":{"rendered":"http:\/\/ft-net.co.jp\/topic\/?p=542"},"modified":"2013-11-12T15:51:01","modified_gmt":"2013-11-12T06:51:01","slug":"%e3%80%8c%e3%83%95%e3%83%83%e7%b4%a0%e7%b3%bb%e9%87%8d%e5%90%88%e8%a7%a6%e5%aa%92%e3%80%8d","status":"publish","type":"post","link":"https:\/\/ft-net.co.jp\/topic\/?p=542","title":{"rendered":"\u300c\u30d5\u30c3\u7d20\u7cfb\u91cd\u5408\u89e6\u5a92\u300d"},"content":{"rendered":"

\u6700\u65b0\u30d5\u30c3\u7d20\u95a2\u9023\u30c8\u30d4\u30c3\u30af\u30b9\u300d\u306f\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u682a\u5f0f\u4f1a\u793e\u30d5\u30a1\u30a4\u30f3\u30b1\u30df\u30ab\u30eb\u90e8\u306e\u3054\u597d\u610f\u306b\u3088\u308a\u3001\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u306eWEB\u30de\u30ac\u30b8\u30f3\u306b\u63b2\u8f09\u3055\u308c\u305f\u5185\u5bb9\u3092\u7d39\u4ecb\u3057\u3066\u3044\u307e\u3059\u3002\u3054\u611b\u9867\u306e\u307b\u3069\u3088\u308d\u3057\u304f\u304a\u9858\u3044\u3044\u305f\u3057\u307e\u3059\u3002\u5c1a\u3001WEB\u30de\u30ac\u30b8\u30f3\u306eURL\u306f\u4e0b\u8a18\u306e\u901a\u308a\u3067\u3059\u3002
\nhttp:\/\/www.daikin.co.jp\/chm\/products\/fine\/backnum\/201310\/#topic01<\/p>\n

1\u3001\u306f\u3058\u3081\u306b
\n \u30d5\u30c3\u7d20\u7cfb\u91cd\u5408\u89e6\u5a92\u3068\u3057\u3066\u306f\u3001\u30ab\u30c1\u30aa\u30f3\u91cd\u5408\u89e6\u5a92\u3068\u3057\u3066BF3\u304c\u4f7f\u7528\u3055\u308c\u3066\u3044\u308b\u3053\u3068\u3001\u3042\u308b\u3044\u306f\u30e1\u30bf\u30ed\u30bb\u30f3\u89e6\u5a92\u306b(C6F5)4B+(C6H5)3C\uff0d\u304c\u52a9\u89e6\u5a92\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u3066\u3044\u308b\u3053\u3068\u306f\u5468\u77e5\u306e\u3053\u3068\u3067\u3042\u308b\u3002\u3053\u3053\u3067\u306f\u3001\u6700\u8fd1\u306e\u6587\u732e\u3001\u7279\u8a31\u304b\u3089\u30d5\u30c3\u7d20\u7cfb\u91cd\u5408\u7528\u89e6\u5a92\u306e\u6700\u8fd1\u306e\u72b6\u6cc1\u3092\u8ff0\u3079\u308b\u3002 <\/p>\n

2\u3001\u30a8\u30c1\u30ec\u30f3\u306e\u91cd\u5408
\nPraserthdam\u3089\u306f\u3001\u4e0b\u56f3\u306b\u793a\u3059\u542b\u30d5\u30c3\u7d20\u30d5\u30a7\u30ce\u30ad\u30b7\u30a4\u30df\u30f3(FI)\u578bTi\u932f\u4f53\u3092\u5408\u6210\u3057\u3001\u30e1\u30c1\u30eb\u30a2\u30eb\u30df\u30ce\u30ad\u30b5\u30f3(MAO)\u3068\u7d44\u307f\u5408\u308f\u305b\u3066\u30a8\u30c1\u30ec\u30f3\u306e\u91cd\u5408\u3092\u884c\u3044\u3001\u8d85\u9ad8\u5206\u5b50\u91cf\u30dd\u30ea\u30a8\u30c1\u30ec\u30f3\u3092\u5f97\u305f\u30021\uff09R\u306e\u90e8\u5206\u304cCl\u3001Br\u3001I\u3067\u3042\u308b3\u7a2e\u985e\u3092\u5408\u6210\u3057\u3001\u3044\u305a\u308c\u3082Mw\u3067300\u4e07\u4ee5\u4e0a\u306e\u8d85\u9ad8\u5206\u5b50\u91cf\u306e\u30dd\u30ea\u30a8\u30c1\u30ec\u30f3\u3092\u5f97\u305f\u3002\u3053\u306e\u4e2d\u3067\u3001Br\u3092\u542b\u3080\u3082\u306e\u304c\u6700\u3082\u9ad8\u3044\u6d3b\u6027\u3092\u793a\u3057\u305f\u3002\u672c\u91cd\u5408\u306f\u30ea\u30d3\u30f3\u30b0\u91cd\u5408\u3067\u3042\u308a\u3001\u5206\u5b50\u91cf\u5206\u5e03\u304c\u72ed\u3044\u3053\u3068\u3082\u7279\u5fb4\u7684\u3067\u3042\u308b\u3002
\n\"FT1\"
\n\"FT2\"
\nHong Fan\u3089\u306f\u3001\u542b\u30d5\u30c3\u7d20FI-Ti\u89e6\u5a92(bis[N-(3-methylsalicylidene)-2,3,4,5,6-\u3000pentafluoroanilinato]TiCl2\/driedMAO)\u3092\u7528\u3044\u3066\u30a8\u30c1\u30ec\u30f3\u306e\u30ea\u30d3\u30f3\u30b0\u91cd\u5408\u3092\u884c\u3044\u3001\u9014\u4e2d\u3067ZnCl2\u3092\u52a0\u3048\u308b\u3053\u3068\u3067\u3001\u30d0\u30a4\u30e2\u30fc\u30c0\u30eb\u5206\u5b50\u91cf\u30dd\u30ea\u30a8\u30c1\u30ec\u30f3\u3092\u5f97\u305f\u30022)\u7d50\u679c\u3092Table1\u306b\u793a\u3059\u3002ZnCl2\u3092\u52a0\u3048\u306a\u3044\u3068\u5206\u5b50\u91cf\u5206\u5e03\u306e\u72ed\u3044\u9ad8\u5206\u5b50\u91cf\u306e\u30dd\u30ea\u30a8\u30c1\u30ec\u30f3\u304c\u5f97\u3089\u308c\u308b\u304c\u3001ZnCl2\u91cf\u3092\u52a0\u3048\u308b\u3068\u5206\u5b50\u91cf\u304c\u4f4e\u4e0b\u3057\u3001\u305d\u306e\u91cf\u3092\u5897\u5927\u3059\u308b\u3068\u3055\u3089\u306b\u4f4e\u4e0b\u3059\u308b\u3002\u305d\u3053\u3067\u3001\u307e\u305a\u306fZnCl2\u3092\u52a0\u3048\u306a\u3044\u89e6\u5a92\u7cfb\u3067\u91cd\u5408\u3092\u884c\u308f\u305b\u3001\u305d\u306e\u5f8cZnCl2\u3092\u52a0\u3048\u3066\u3055\u3089\u306b\u7d9a\u3051\u308b\u3053\u3068\u3067\u3001\u30d0\u30a4\u30e2\u30fc\u30c0\u30eb\u306a\u5206\u5b50\u91cf\u5206\u5e03\u3092\u6301\u3063\u305f\u30dd\u30ea\u30de\u30fc\u304c\u5f97\u3089\u308c\u305f\u3002
\n\"FT3\"
\n\u4e0b\u56f3\u306b\u304a\u3044\u3066\u3001Run3\u306fTable1\u306e\u6761\u4ef6\u3001Run10\u306f\u3001Zn\/Ti=180\u306715\u5206\u9593\u91cd\u5408\u3001Run11\u306f\u6700\u521d\u306e5\u5206\u9593\u306fZn\/Ti=0\u3067\u3001\u305d\u306e\u5f8cZnCl2\u3092\u6dfb\u52a0\u3057\u3001Zn\/Ti=180\u306e\u72b6\u614b\u306715\u5206\u9593\u91cd\u5408\u3057\u305f\u3002
\n\"FT4\"
\n3\u3001\u03b1-\u30aa\u30ec\u30d5\u30a3\u30f3\u306e\u91cd\u5408
\nE.P.Talsi\u3089\u306f\u3001\u03b1-\u30aa\u30ec\u30d5\u30a3\u30f3\u306e\u914d\u4f4d\u91cd\u5408\u306b\u3064\u3044\u3066\u306e\u7dcf\u8aac\u3092\u5831\u544a\u3057\u3066\u3044\u308b\u304c\u3001\u305d\u306e\u4e2d\u3067\u542b\u30d5\u30c3\u7d20\u914d\u4f4d\u5b50\u3092\u6709\u3059\u308b\u932f\u4f53\u89e6\u5a92\u306b\u3064\u3044\u3066\u306e\u8a18\u8ff0\u3092\u629c\u7c8b\u3057\u305f\u30023)<\/p>\n

\u307e\u305a\u306f\u3001\u30e1\u30bf\u30ed\u30bb\u30f3\u89e6\u5a92\u306b\u3064\u3044\u3066\u3067\u3042\u308b\u304c\u3001\u4e0b\u56f3\u306b\u793a\u3059MeB(C6F5)3\uff0d\u3001B(C6F5)4\uff0d\u3092\u914d\u4f4d\u5b50\u3068\u3059\u308b\u30e1\u30bf\u30ed\u30bb\u30f3\u89e6\u5a92(M=Ti\u3042\u308b\u3044\u306fZr)\u306b\u304a\u3044\u3066\u3001A\u306e\u5185\u570f\u578b\u3001B\u3001C\u306e\u5916\u570f\u578b\u30a4\u30aa\u30f3\u30da\u30a2\u304cB\/M\u304c\u307b\u307c1\u306e\u6642\u306b\u5b58\u5728\u3059\u308b\u3002\u307e\u305f\u30011\u30847\u306e\u30d5\u30a7\u30ce\u30ad\u30b7\u30a4\u30df\u30f3\u932f\u4f53\u306fMAO\u3084AlMe3\/[CPh3][B(C6F5)4]\u3067\u6d3b\u6027\u5316\u3055\u308c\u308b\u304c\u3001C\u578b\u306e\u30a4\u30aa\u30f3\u30da\u30a2\u306f\u5f62\u6210\u305b\u305a\u3001B\u578b\u306e\u30a4\u30aa\u30f3\u30da\u30a2\u3092\u5f62\u6210\u3059\u308b\u3002\u5185\u570f\u578b\u30a4\u30aa\u30f3\u30da\u30a2A\u306f\u5916\u570f\u578bB\u306b\u6bd4\u3057\u3066\u89e6\u5a92\u6d3b\u6027\u304c\u4f4e\u3044\u3002\u3053\u308c\u306fCH3B(C6F5)3\uff0d\u306e\u65b9\u304cB(C6F5)4\uff0d\u306b\u6bd4\u3079\u3066\u914d\u4f4d\u529b\u304c\u5f37\u304f\u3001\u4e2d\u5fc3\u91d1\u5c5e\u304b\u3089\u96e2\u308c\u306b\u304f\u3044\u304b\u3089\u3060\u3068\u3057\u3066\u3044\u308b\u3002
\n\"FT5\"
\n\u307e\u305f\u3001\u4e0b\u56f3\u306e\u932f\u4f53\u306f1-\u30d8\u30ad\u30bb\u30f3\u306e\u91cd\u5408\u306b\u304a\u3044\u3066\u89e6\u5a92\u306e\u30a8\u30fc\u30b8\u30f3\u30b0\u3068\u3068\u3082\u306b\u76f4\u7dda\u7684\u306b\u5206\u5b50\u91cf\u304c\u5897\u5927\u3059\u308b\u3002\u3053\u306e\u5834\u5408\u300113a\u304c13b\u306b\u5909\u5316\u3057\u3066\u3044\u308b\u3053\u3068\u3092\u7a81\u304d\u6b62\u3081\u3066\u3044\u308b\u3002
\n\"FT6\"
\n\u3055\u3089\u306b\u30011\u30847\u306e\u932f\u4f53\u89e6\u5a92\u306b\u304a\u3044\u3066\u3001F\u539f\u5b50\u304c\u30aa\u30eb\u30c8\u4f4d\u306b\u3042\u308b\u3068\u30ea\u30d3\u30f3\u30b0\u91cd\u5408\u304c\u53ef\u80fd\u306b\u306a\u308b\u3068\u306e\u898b\u89e3\u3092\u793a\u3057\u3066\u3044\u308b\u3002\u4f8b\u3048\u3070\u4e0b\u56f3\u306b\u304a\u3044\u3066\u3001\u30aa\u30eb\u30c8\u4f4d\u306eF\u304cTi\u3068\u76f4\u63a5\u76f8\u4e92\u4f5c\u7528\u3057\u3066\u3044\u308b\u3053\u3068\u3092NMR\u3067\u691c\u8a3c\u3057\u3001\u3053\u306e\u76f8\u4e92\u4f5c\u7528\u304c\u9396\u6210\u9577\u90e8\u4f4d\u306b\u5f37\u304f\u5f71\u97ff\u3057\u3001\u9023\u9396\u79fb\u52d5\u53cd\u5fdc\u3092\u963b\u6b62\u3057\u3066\u3044\u308b\u3068\u3057\u3066\u3044\u308b\u3002
\n\"FT7\"
\n4\u3001\u958b\u74b0\u91cd\u5408
\nR. J. Baker\u3089\u306f\u3001\u4e0b\u5f0f\u306e\u65b9\u6cd5\u3067\u5408\u6210\u3057\u305fRf(C6F13C2H4)\u57fa\u542b\u6709Zn\u932f\u4f53\u306b\u3088\u308b\u03b5-\u30ab\u30d7\u30ed\u30e9\u30af\u30bf\u30e0\u306e\u958b\u74b0\u91cd\u5408\u306b\u3064\u3044\u3066\u5831\u544a\u3057\u3066\u3044\u308b(\u4e0b\u8868)\u30024)
\n\"FT0\"<\/p>\n

\"FT8\"<\/p>\n

\u3053\u3053\u3067\u3001BnOH\u306f\u30d9\u30f3\u30b8\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u3001THF\u306f\u6eb6\u5a92\u30c6\u30c8\u30e9\u30d2\u30c9\u30ed\u30d5\u30e9\u30f3\u3067\u3042\u308b\u3002\u672c\u30d5\u30eb\u30aa\u30e9\u30b9\u89e6\u5a92\u306f1\uff0c3\u30d3\u30b9\u30c8\u30ea\u30d5\u30eb\u30aa\u30ed\u30e1\u30c1\u30eb\u30d9\u30f3\u30bc\u30f3\u306e\u3088\u3046\u306a\u30d5\u30c3\u7d20\u7cfb\u6eb6\u5a92\u306b\u6eb6\u3051\u308b\u306e\u3067\u30ea\u30b5\u30a4\u30af\u30eb\u304c\u5bb9\u6613\u3067\u3042\u308b\u304c\u3001\u30d9\u30f3\u30b8\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u3092\u958b\u59cb\u5264\u3068\u3057\u305f\u3068\u304d\u306f\u30ea\u30b5\u30a4\u30af\u30eb\u304c\u56f0\u96e3\u306b\u306a\u308b\u3002<\/p>\n

5\u3001\u304a\u308f\u308a\u306b<\/p>\n

\u3053\u306e\u307b\u304b\u306b\u3001CO2\u3068\u30a8\u30dd\u30ad\u30b7\u5316\u5408\u7269\u3068\u306e\u5171\u91cd\u5408\u306b\u304a\u3044\u3066\u3001\u542b\u30d5\u30c3\u7d20Zn\u4e8c\u6838\u932f\u4f53\u3092\u89e6\u5a92\u3068\u3059\u308b\u3068\u9023\u9396\u79fb\u52d5\u306e\u5c11\u306a\u3044\u30dd\u30ea\u30de\u30fc\u304c\u5f97\u3089\u308c\u305f\u3068\u306e\u5831\u544a\u306a\u3069\u304c\u3042\u308b\u30025)<\/p>\n

\u30d5\u30c3\u7d20\u7cfb\u91cd\u5408\u89e6\u5a92\u304c\u30aa\u30ec\u30d5\u30a3\u30f3\u306e\u30ea\u30d3\u30f3\u30b0\u91cd\u5408\u306b\u91cd\u8981\u306a\u5f79\u5272\u3092\u6f14\u3058\u3066\u3044\u308b\u3053\u3068\u306f\u8208\u5473\u6df1\u3044\u3002\u307e\u305f\u3001\u30d5\u30eb\u30aa\u30e9\u30b9\u89e6\u5a92\u306e\u30ea\u30b5\u30a4\u30af\u30eb\u6027\u306b\u3082\u6ce8\u76ee\u3057\u305f\u3044\u3002<\/p>\n

\u6587\u732e<\/p>\n

1) Piyasan Praserthdam et al Polymer 54(2013) 3217-3222
\n 2) Hong Fan et al European Polymer Journal 49(2013) 1823-1831
\n 3) Evgenii P. Talsi et al Coordination Chemistry Reviews 256(2012) 2994-3007
\n 4) Robert J. Baker et al Journal of Fluorine Chemistry 139(2012) 58-62
\n 5) Bernhard Rieger et al Coordination Chemistry Reviews 255(2011) 1460-1479<\/p>\n","protected":false},"excerpt":{"rendered":"

\u6700\u65b0\u30d5\u30c3\u7d20\u95a2\u9023\u30c8\u30d4\u30c3\u30af\u30b9\u300d\u306f\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u682a\u5f0f\u4f1a\u793e\u30d5\u30a1\u30a4\u30f3\u30b1\u30df\u30ab\u30eb\u90e8\u306e\u3054\u597d\u610f\u306b\u3088\u308a\u3001\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u306eWEB\u30de\u30ac\u30b8\u30f3\u306b\u63b2\u8f09\u3055\u308c\u305f\u5185\u5bb9\u3092\u7d39\u4ecb\u3057\u3066\u3044\u307e\u3059\u3002\u3054\u611b\u9867\u306e\u307b\u3069\u3088\u308d\u3057\u304f\u304a\u9858\u3044\u3044\u305f\u3057\u307e\u3059\u3002\u5c1a\u3001WEB\u30de\u30ac\u30b8\u30f3\u306eURL … \u7d9a\u304d\u3092\u8aad\u3080<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"class_list":["post-542","post","type-post","status-publish","format-standard","hentry","category-1"],"_links":{"self":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts\/542","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=542"}],"version-history":[{"count":4,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts\/542\/revisions"}],"predecessor-version":[{"id":560,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts\/542\/revisions\/560"}],"wp:attachment":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=542"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=542"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=542"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}