{"id":535,"date":"2013-09-05T11:50:51","date_gmt":"2013-09-05T02:50:51","guid":{"rendered":"http:\/\/ft-net.co.jp\/topic\/?p=535"},"modified":"2013-11-12T15:51:01","modified_gmt":"2013-11-12T06:51:01","slug":"%e3%80%8c%e3%83%95%e3%83%83%e7%b4%a0%e7%b3%bb%e3%83%8a%e3%83%8e%e3%82%b3%e3%83%b3%e3%83%9d%e3%82%b8%e3%83%83%e3%83%88%e3%80%8d","status":"publish","type":"post","link":"https:\/\/ft-net.co.jp\/topic\/?p=535","title":{"rendered":"\u300c\u30d5\u30c3\u7d20\u7cfb\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u300d"},"content":{"rendered":"

\u6700\u65b0\u30d5\u30c3\u7d20\u95a2\u9023\u30c8\u30d4\u30c3\u30af\u30b9\u300d\u306f\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u682a\u5f0f\u4f1a\u793e\u30d5\u30a1\u30a4\u30f3\u30b1\u30df\u30ab\u30eb\u90e8\u306e\u3054\u597d\u610f\u306b\u3088\u308a\u3001\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u306eWEB\u30de\u30ac\u30b8\u30f3\u306b\u63b2\u8f09\u3055\u308c\u305f\u5185\u5bb9\u3092\u7d39\u4ecb\u3057\u3066\u3044\u307e\u3059\u3002\u3054\u611b\u9867\u306e\u307b\u3069\u3088\u308d\u3057\u304f\u304a\u9858\u3044\u3044\u305f\u3057\u307e\u3059\u3002\u5c1a\u3001WEB\u30de\u30ac\u30b8\u30f3\u306eURL\u306f\u4e0b\u8a18\u306e\u901a\u308a\u3067\u3059\u3002
\nhttp:\/\/www.daikin.co.jp\/chm\/products\/fine\/backnum\/201309\/#topic01<\/p>\n

1\u3001\u306f\u3058\u3081\u306b
\n \u30d5\u30c3\u7d20\u30dd\u30ea\u30de\u30fc\uff0f\u7121\u6a5f\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u306e\u958b\u767a\u304c\u76db\u3093\u3060\u3002\u30d5\u30c3\u7d20\u30dd\u30ea\u30de\u30fc\u306e\u8010\u71b1\u6027\u3001\u8868\u9762\u7279\u6027\u306a\u3069\u306e\u7279\u5fb4\u3092\u6d3b\u304b\u3057\u306a\u304c\u3089\u6a5f\u68b0\u7684\u5f37\u5ea6\u306e\u5411\u4e0a\u3001\u4f4e\u30b3\u30b9\u30c8\u5316\u3092\u56f3\u308b\u3053\u3068\u306f\u52ff\u8ad6\u306e\u3053\u3068\u3001\u8d85\u64a5\u6c34\u30fb\u64a5\u6cb9\u6750\u6599\u3001\u56fa\u4f53\u89e6\u5a92\u3001\u30ac\u30b9\u900f\u904e\u6027\u819c\u3001\u9ad8\u8a98\u96fb\u7387\u4f53\u3001\u4f4e\u8a98\u96fb\u7387\u30fb\u9ad8\u5f37\u5ea6\u6750\u6599\u306a\u3069\u3092\u30bf\u30fc\u30b2\u30c3\u30c8\u306b\u591a\u5f69\u306a\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u304c\u958b\u767a\u3055\u308c\u3066\u3044\u308b\u3002\u307e\u305f\u3001\u30d5\u30c3\u7d20\u30dd\u30ea\u30de\u30fc\u3068\u4ed6\u306e\u30a8\u30f3\u30d7\u30e9\u3068\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u5316\u306b\u3088\u308a\u305d\u308c\u305e\u308c\u306e\u7279\u5fb4\u3092\u767a\u63ee\u3059\u308b\u30dd\u30ea\u30de\u30fc\u30a2\u30ed\u30a4\u306e\u5831\u544a\u3082\u306a\u3055\u308c\u3066\u3044\u308b\u3002\u3053\u3053\u3067\u306f\u3001\u3053\u308c\u3089\u306e\u6587\u732e\u60c5\u5831\u3092\u307e\u3068\u3081\u3066\u307f\u305f\u3002 <\/p>\n

2\u3001\u30d5\u30c3\u7d20\u7cfb\u30dd\u30ea\u30de\u30fc\uff0f\u7121\u6a5f\u5316\u5408\u7269\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8
\n\u4e2d\u56fd\u306e\u7814\u7a76\u8005\u306b\u3088\u308b\u7121\u6a5f\u5316\u5408\u7269\u3068\u30d5\u30c3\u7d20\u30dd\u30ea\u30de\u30fc\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u306e\u7814\u7a76\u304c\u76db\u3093\u3067\u3042\u308b\u3002
\nChengxue Zhao\u3089\u306f\u3001\u4e0b\u56f3\u5de6\u306e\u03c9-\u30b9\u30eb\u30d5\u30a9\u30cb\u30c3\u30af\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u5316\u30dd\u30ea(\u30b9\u30c1\u30ec\u30f3\u2010\u7121\u6c34\u30de\u30ec\u30a4\u30f3\u9178)\uff0f\u30b7\u30ea\u30ab\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u3092\u5408\u6210\u3057\u305f\u30021\uff09\u65b0\u898f\u306a\u89e6\u5a92\u3068\u3057\u3066\u3001\u30d7\u30bd\u30a4\u30c9\u30e8\u30ce\u30f3\u306e\u74b0\u5316\u53cd\u5fdc\u3001\u30a4\u30f3\u30c9\u30fc\u30eb\u306e\u7e2e\u5408\u53cd\u5fdc\u3001\u5b89\u606f\u9999\u9178\u306e\u30a8\u30b9\u30c6\u30eb\u5316\u53cd\u5fdc\u306b\u304a\u3044\u3066Nafion\/SiO2\u3068\u540c\u7b49\u4ee5\u4e0a\u306e\u9ad8\u3044\u6d3b\u6027\u3092\u78ba\u8a8d\u3057\u3066\u3044\u308b\u3002
\n\u307e\u305f\u3001Ling He\u3089\u306f\u30e1\u30c8\u30ad\u30b7\u30b7\u30e9\u30f3\u3067\u51e6\u7406\u3057\u305fSiO2\u3092\u30b3\u30a2\u3068\u3057\u3001CF3CH2OCOC(CH3)=CH2\uff0fMMA\uff0fBA\u306e\u5171\u91cd\u5408\u4f53\u3092\u30b0\u30e9\u30d5\u30c8\u91cd\u5408\u306b\u3088\u308a\u30b7\u30a7\u30eb\u3068\u3059\u308b\u30b3\u30a2\u30fb\u30b7\u30a7\u30eb\u30bf\u30a4\u30d7\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u3092\u5408\u6210\u3057(\u4e0b\u56f3\u53f3)\u3001\u305d\u306e\u5206\u6563\u6027\u3092\u8abf\u3079\u305f\u30022\uff09\u305d\u306e\u7d50\u679c\u3001SiO2\u3092CH=C(CH3)COOC3H6Si(OCH3)3\u3067\u51e6\u7406\u3057\u305f\u65b9\u304cCH2=CHSi(OCH3)3\u3067\u51e6\u7406\u3057\u305f\u3088\u308a\u3082\u30b0\u30e9\u30d5\u30c8\u7387\u306f\u9ad8\u304f\u3001\u6709\u6a5f\u6eb6\u5a92\u3078\u306e\u5206\u6563\u6027\u304c\u9ad8\u3044\u3053\u3068\u304c\u5206\u304b\u3063\u305f\u3002\u672c\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u306f\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u7528\u9014\u3068\u3057\u3066\u6709\u671b\u3067\u64a5\u6c34\u6027\u3001\u8010\u71b1\u6027\u3001\u8010\u85ac\u54c1\u6027\u304c\u671f\u5f85\u3067\u304d\u308b\u3068\u3057\u3066\u3044\u308b\u3002
\n\"FT1\"
\n\u6b21\u3044\u3067\u3001Xiaoyun Liu\u3089\u306f\u3001\u4e0b\u56f3\u306b\u793a\u30596FPBOT\uff0fPOSS\u3068\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u3092\u4f5c\u88fd\u3057\u3001\u512a\u308c\u305f\u8010\u71b1\u6027\u3001\u6a5f\u68b0\u7684\u7279\u6027\u30682.11\u3068\u3044\u3046\u4f4e\u3044\u8a98\u96fb\u7387\u3092\u78ba\u8a8d\u3057\u3066\u3044\u308b\u3002\uff086FPBOT\u306f2.56\uff093)
\n\"FT2\"
\n\u3055\u3089\u306b\u3001Hequing Hu\u3089\u306f\u3001(HOC2H4)2(C12H24)CH3N+Cl\u3067\u4fee\u98fe\u3055\u308c\u305f\u6709\u6a5f\u30e2\u30f3\u30e2\u30ea\u30ed\u30ca\u30a4\u30c8\uff08OMMT\uff09\u3068\u6c34\u7cfb\u542b\u30d5\u30c3\u7d20\u30dd\u30ea\u30a6\u30ec\u30bf\u30f3(FWPU)\u3068\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u30a8\u30de\u30eb\u30b8\u30e7\u30f3\u3092\u5408\u6210\u3057\u3001\u305d\u306e\u30d5\u30a3\u30eb\u30e0\u306e\u7279\u5fb4\u3092\u8abf\u3079\u305f\u30024\uff09\u5408\u6210\u306fCF3CHFCF2CH2OCOC(CH3)=CH2\u3068\u30dd\u30ea\u30d6\u30c1\u30ec\u30f3\u30a2\u30b8\u30da\u30fc\u30c8\u30b0\u30ea\u30b3\u30fc\u30eb\u3068\u30a4\u30bd\u30db\u30ed\u30f3\u30b8\u30a4\u30bd\u30b7\u30a2\u30cd\u30fc\u30c8\u304b\u3089\u5408\u6210\u3057\u305f\u30dd\u30ea\u30a6\u30ec\u30bf\u30f3\u3092OMMT\u3068HOC2H4OCOCH=CH2\u3067\u4fee\u98fe\u3057\u305f\u30de\u30af\u30ed\u30e2\u30ce\u30de\u30fc\u3068\u306e\u30a8\u30de\u30eb\u30b7\u30e7\u30f3\u30b7\u30fc\u30c9\u91cd\u5408\u3067\u884c\u3063\u305f\u3002\u8010\u71b1\u6027\u306fOMMT\u30b3\u30f3\u30c6\u30f3\u30c8\u3068\u3068\u3082\u306b\u4e0a\u304c\u3063\u305f\u3002\u6a5f\u68b0\u7684\u5f37\u5ea6\u306fOMMT\u304c2%\u306e\u6642\u6700\u5927\u3067\u3042\u308a\u3001\u64a5\u6c34\u6027\u306fFWPU\u306e\u30b3\u30f3\u30c6\u30f3\u30c8\u304c\u5897\u3048\u308b\u3068\u5897\u5927\u3057\u305f\u3002
\nB. J. Bath\u3089\u306f\u3001\u30dd\u30ea\u30b8\u30e1\u30c1\u30eb\u30b7\u30ed\u30ad\u30b5\u30f3\uff0f\u30b7\u30ea\u30ab\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u306bC6F13C2H4Si(OCH3)3\uff08FAS-13\uff09\u3092\u30b3\u30fc\u30c6\u30a4\u30f3\u30b0\u3057\u3066\u3001\u4e0b\u8868\u306b\u793a\u3059\u3088\u3046\u306b\u6c34\u306e\u63a5\u89e6\u89d2158\u5ea6\u3001\u6cb9\u306e\u63a5\u89e6\u89d279\u5ea6\u3092\u5f97\u3066\u3044\u308b\u30025\uff09\u3053\u3053\u3067\u3001a\u306fFAS-13\u30922\u56de\u3001b\u306f4\u56de\u3001c\u306f6\u56de\u30b9\u30d7\u30ec\u30fc\u3092\u3057\u3066\u3044\u308b\u304c\u3001\u5927\u5dee\u306f\u306a\u3044\u3002
\n\"FT3\"
\nG. Weber\u3089\u306f\u3001TeflonAF\u3068C6F13C2H4Si(OCH3)3\u3067\u4fee\u98fe\u3055\u308c\u305f\u30b7\u30ea\u30ab\uff08FNP\uff09\u304a\u3088\u3073FC-70\u3068\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u3092\u4f5c\u88fd\u3057\u3001\u30da\u30f3\u30bf\u30d5\u30eb\u30aa\u30ed\u30cb\u30c8\u30ed\u30d9\u30f3\u30bc\u30f3\u306a\u3069\u306e\u30d5\u30eb\u30aa\u30e9\u30b9\u6db2\u4f53\u306e\u900f\u904e\u6027\u3092\u8abf\u3079\u3066\u3044\u308b\u30026\uff09\u6db2\u4f53\u900f\u904e\u6027\u306b\u5f71\u97ff\u3059\u308b\u306e\u306f\u30d5\u30a3\u30eb\u30e0\u306e\u81ea\u7531\u4f53\u7a4d\u3067\u3042\u308b\u3068\u3057\u3066\u3044\u308b\u3002TeflonAF\u306b\u3064\u3044\u3066\u306f\u3001\u30ac\u30e9\u30b9\u72b6(\u9ad8Tg)\u304b\u53ef\u5851\u5316\u72b6(\u4f4eTg)\u304b\u306b\u3088\u308a\u7570\u306a\u308a\u3001\u524d\u8005\u3067\u7279\u306bFNP\u306ewt%\u304c\u9ad8\u3044\u7cfb\u3067\u306fFNP\u306e\u5468\u308a\u306b\u8513\u304c\u5dfb\u304d\u3064\u3044\u305f\u3088\u3046\u306a\u5f62\u3092\u3057\u3066\u3044\u308b\u304c\u3001\u5f8c\u8005\u306e\u5834\u5408\u306f\u3001FNP\u3092\u30b3\u30a2\u3068\u3057\u3001TeflonAF\u3092\u30b7\u30a7\u30eb\u3068\u3059\u308b\u30b3\u30a2\u30fb\u30b7\u30a7\u30eb\u69cb\u9020\u3092\u5f62\u6210\u3057\u3066\u3044\u308b\u3002\u3044\u305a\u308c\u3082\u307f\u304b\u3051\u306e\u81ea\u7531\u4f53\u7a4d\u5206\u7387\u306f\u7d0450%\u3068\u9ad8\u304b\u3063\u305f\u3002\u307e\u305f\u3001\u308f\u305a\u304b10wt%\u306eTeflonAF\u306e\u30b3\u30f3\u30c6\u30f3\u30c8\u3067\u6e80\u8db3\u306a\u30d5\u30a3\u30eb\u30e0\u304c\u5f62\u6210\u3055\u308c\u3001\u30d5\u30eb\u30aa\u30e9\u30b9\u6db2\u4f53\u306e\u9078\u629e\u7684\u5206\u96e2\u304c\u53ef\u80fd\u306b\u306a\u3063\u305f\u3068\u3057\u3066\u3044\u308b\u3002
\nStefan B. Ebbinghaus\u3089\u306f\u3001P(VDF-HFP)\u3068BaTiO3\u3068\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u3092\u4f5c\u88fd\u3057\u3001\u30d5\u30a3\u30eb\u30e0\u30b3\u30f3\u30c7\u30f3\u30b5\u30fc\u306e\u7d76\u7e01\u8a98\u5c0e\u4f53\u3068\u3057\u3066\u8a55\u4fa1\u3057\u305f\u30027\uff09BaTiO3\u30ca\u30ce\u7c92\u5b50\u306f\u30be\u30eb\u30b2\u30eb\u6cd5\u3067\u4f5c\u88fd\u3057\u3001n-\u30aa\u30af\u30c1\u30eb\u30db\u30b9\u30db\u30f3\u9178\u30682,3,4,5,6-\u30da\u30f3\u30bf\u30d5\u30eb\u30aa\u30ed\u30db\u30b9\u30db\u30f3\u9178\u3092\u7528\u3044\u3066\u4e8c\u6b21\u7c92\u5b50\u5316\u3092\u9632\u3044\u3067\u3044\u308b\u3002\u305d\u306e\u7cfb\u3092P(VDF-HFP)\u6eb6\u6db2\u306b\u5206\u6563\u3055\u305b\u3066\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u3092\u4f5c\u88fd\u3057\u305f\u3002\u672c\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u306fP(VDF-HFP)\u306e5\u500d\u306e\u7d76\u5bfe\u8a98\u96fb\u7387\u3092\u6709\u3057\u3066\u304a\u308a\u3001\u30d5\u30a3\u30eb\u30e0\u30b3\u30f3\u30c7\u30f3\u30b5\u30fc\u3068\u3057\u3066\u6709\u671b\u3068\u3057\u3066\u3044\u308b\u3002
\nIlker S. Bayer\u3089\u306f\u3001MWCNT\u3068\u30d5\u30eb\u30aa\u30ed\u30a2\u30af\u30ea\u30ec\u30fc\u30c8\u5171\u91cd\u5408\u4f53(\u30c7\u30e5\u30dd\u30f3\u793e\u306eCapstone ST-100\u3000\u77f3\u6750\u7528\u64a5\u6c34\u64a5\u6cb9\u5264)\u3068\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u3092\u4f5c\u88fd\u3057\u3001\u64a5\u6c34\u6027\u3092\u8a55\u4fa1\u3057\u305f\u30028\uff09\u305d\u306e\u7d50\u679c\u3001\u4e0b\u56f3\u306b\u793a\u3059\u3088\u3046\u306b\u98a8\u4e7e(a)\u3067MWCNT10%\u4ee5\u4e0a\u3067150\u5ea6\u3092\u8d85\u3048\u308b\u8d85\u64a5\u6c34\u6027\u3092\u793a\u3057\u3001\u3055\u3089\u306b165\u2103\u3067\u30ad\u30e5\u30a2\u3059\u308b(b)\u3068\u540c\u3058\u304fMWCNT10% \u4ee5\u4e0a\u3067165\u5ea6\u3092\u8d85\u3048\u308b\u8d85\u64a5\u6c34\u6027\u3092\u793a\u3057\u305f\u3002
\n\"FT4\"<\/p>\n

3\u3001\u30d5\u30c3\u7d20\u30dd\u30ea\u30de\u30fc\uff0fPEEK\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8
\n\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u3068\u30c0\u30a4\u30bb\u30eb\u306f\u3001PEEK\u4e2d\u306b\u30d5\u30c3\u7d20\u6a39\u8102\u304c\u30ca\u30ce\u30aa\u30fc\u30c0\u30fc\u3067\u5206\u6563\u3059\u308b\u65b0\u898f\u30a2\u30ed\u30a4\u306e\u958b\u767a\u306b\u6210\u529f\u3057\u305f\u30029)
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\n\"FT5\"
\n4\u3001\u304a\u308f\u308a\u306b
\n\u30d5\u30c3\u7d20\u30dd\u30ea\u30de\u30fc\u3068\u7121\u6a5f\u5316\u5408\u7269\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u306f\u4e2d\u56fd\u306b\u304a\u3044\u3066\u76db\u3093\u3067\u3042\u308b\u304c\u3001\u4eca\u306e\u3068\u3053\u308d\u753b\u671f\u7684\u306a\u7d50\u679c\u306b\u306f\u81f3\u3063\u3066\u3044\u306a\u3044\u3002\u3057\u304b\u3057\u3001\u8d85\u64a5\u6c34\u6027\u30fb\u9ad8\u64a5\u6cb9\u6027\u6750\u6599\u3001\u6db2\u4f53\u5206\u96e2\u819c\u3001\u7d76\u7e01\u8a98\u5c0e\u4f53\u306a\u3069\u591a\u5f69\u306a\u30a2\u30d7\u30ea\u30b1\u30fc\u30b7\u30e7\u30f3\u304c\u691c\u8a0e\u3055\u308c\u3066\u304a\u308a\u3001\u4eca\u5f8c\u306b\u671f\u5f85\u3057\u305f\u3044\u3002\u307e\u305f\u3001\u30a8\u30f3\u30d7\u30e9\u3068\u30d5\u30c3\u7d20\u6a39\u8102\u3068\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u306b\u304a\u3044\u3066\u5927\u3044\u306a\u308b\u53ef\u80fd\u6027\u304c\u5f97\u3089\u308c\u3066\u304a\u308a\u3001\u30d5\u30c3\u7d20\u30dd\u30ea\u30de\u30fc\u3068\u4ed6\u6750\u6599\u3068\u306e\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u306f\u3001\u4eca\u5f8c\u76ee\u304c\u96e2\u305b\u306a\u3044\u30c6\u30fc\u30de\u3067\u3042\u308b\u3068\u8003\u3048\u3066\u3044\u308b\u3002<\/p>\n

\u7279\u8a31
\n1) Chengxue Zhao et al Journal of Molecular Catalysis\uff1aA365(2012)\u300073-79
\n 2) Ling He et al Journal of Colloid and Intersurface396(2013)129-137
\n 3) Xiaoyun Liu et al Synthetic Metals 175(2013) 112-119
\n4) Hequing Fu et al Composites Science and Technology 85(2013) 65-72
\n 5) B. J. Bath et al Applied Surface Science 261(2012) 807-814
\n 6) G. Weber et al Journal of Membrane Science 443(2013) 115-123
\n 7) Stefan B. Ebbinfhaus et al Material Science and Engineering B 178(2013) 881-888
\n 8) Ilker S. Bayer et al Chemical Engineering Journal 221(2013) 522-530
\n 9) \u516d\u7530\u5145\u8f1d\u3000\u30d7\u30e9\u30b9\u30c1\u30c3\u30af\u30a8\u30fc\u30b82013\u5e744\u6708\u53f7\u3000100-104<\/p>\n","protected":false},"excerpt":{"rendered":"

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