{"id":501,"date":"2013-04-15T14:47:29","date_gmt":"2013-04-15T05:47:29","guid":{"rendered":"http:\/\/ft-net.co.jp\/topic\/?p=501"},"modified":"2013-11-12T15:51:01","modified_gmt":"2013-11-12T06:51:01","slug":"%e3%80%8c%e8%b6%85%e6%92%a5%e6%b2%b9%e6%80%a7%e3%80%8d","status":"publish","type":"post","link":"https:\/\/ft-net.co.jp\/topic\/?p=501","title":{"rendered":"\u300c\u8d85\u64a5\u6cb9\u6027\u300d"},"content":{"rendered":"

\u6700\u65b0\u30d5\u30c3\u7d20\u95a2\u9023\u30c8\u30d4\u30c3\u30af\u30b9\u300d\u306f\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u682a\u5f0f\u4f1a\u793e\u30d5\u30a1\u30a4\u30f3\u30b1\u30df\u30ab\u30eb\u90e8\u306e\u3054\u597d\u610f\u306b\u3088\u308a\u3001\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u306eWEB\u30de\u30ac\u30b8\u30f3\u306b\u63b2\u8f09\u3055\u308c\u305f\u5185\u5bb9\u3092\u7d39\u4ecb\u3057\u3066\u3044\u307e\u3059\u3002\u3054\u611b\u9867\u306e\u307b\u3069\u3088\u308d\u3057\u304f\u304a\u9858\u3044\u3044\u305f\u3057\u307e\u3059\u3002\u5c1a\u3001WEB\u30de\u30ac\u30b8\u30f3\u306eURL\u306f\u4e0b\u8a18\u306e\u901a\u308a\u3067\u3059\u3002
\nhttp:\/\/www.daikin.co.jp\/chm\/products\/fine\/backnum\/201304\/#topic01<\/p>\n

1\u3001\u306f\u3058\u3081\u306b
\n\u8d85\u64a5\u6cb9\u6027\u306b\u3064\u3044\u3066\u306f\u3001\u3053\u306e\u30b7\u30ea\u30fc\u30ba\u30672012\u5e742\u6708\u53f7\u306b\u304a\u3044\u3066\u300c\u8d85\u64a5\u6c34\u64a5\u6cb9\u8868\u9762\u300d\u3068\u984c\u3057\u3066\u53d6\u308a\u4e0a\u3052\u305f\u3002\u8d85\u64a5\u6c34\u6027\u306b\u95a2\u3057\u3066\u306f\u30d5\u30c3\u7d20\u7cfb\u4ee5\u5916\u306e\u6750\u6599\u3067\u3082\u9054\u6210\u53ef\u80fd\u3067\u3042\u308b\u304c\u3001\u30d5\u30c3\u7d20\u306e\u7279\u5fb4\u3092\u969b\u7acb\u305f\u305b\u308b\u306e\u306f\u8d85\u64a5\u6cb9\u6027\u8868\u9762\u3067\u3042\u308a\u3001\u6700\u8fd1\u3001\u7dcf\u8aac\u3092\u306f\u3058\u3081\u3068\u3057\u3066\u305d\u306e\u95a2\u9023\u306e\u6587\u732e\u3092\u3088\u304f\u76ee\u306b\u3059\u308b\u3002\u672c\u7a3f\u3067\u306f\u305d\u306e\u7dcf\u8aac\u3092\u4e2d\u5fc3\u306b\u6700\u65b0\u306e\u6587\u732e\u3092\u7d39\u4ecb\u3059\u308b\u3002 <\/p>\n

2\u3001\u751f\u4f53\u306b\u5b66\u3076\u8d85\u64a5\u6cb9\u6027\u304a\u3088\u3073\u30b9\u30de\u30fc\u30c8\u7269\u8cea\u306b\u95a2\u3059\u308b\u7dcf\u8aac1)<\/p>\n

\u751f\u7269\u306b\u5b66\u3076\u3068\u3044\u3046\u89b3\u70b9\u3067\u306e\u8d85\u64a5\u6cb9\u6027\u304a\u3088\u3073\u30b9\u30de\u30fc\u30c8\u7269\u8cea\u306b\u95a2\u3057\u305f\u7dcf\u8aac\u3067\u3042\u308b\u3002\u8d85\u64a5\u6c34\u6027\u7269\u8cea\u306b\u3064\u3044\u3066\u306f\u3001\u751f\u4f53\u7269\u8cea\u306b\u304a\u3044\u3066\u591a\u304f\u898b\u3089\u308c\u308b\u304c\u3001\u8d85\u64a5\u6cb9\u6027\u306b\u3064\u3044\u3066\u306f\u7a00\u6709\u3067\u3042\u308b\u3002\u3053\u3053\u3067\u306f\u3001\u307e\u305a\u6fe1\u308c\u6027\u306b\u3064\u3044\u3066\u306e\u7406\u8ad6\u7684\u306a\u80cc\u666f\u3068\u8d85\u64a5\u6cb9\u6027\u7269\u8cea\u306e\u4f4d\u7f6e\u3065\u3051\u3092\u884c\u3044\u3001\u8d85\u64a5\u6cb9\u30fb\u8d85\u64a5\u6c34\u8868\u9762\u3001\u64a5\u6cb9\u30fb\u89aa\u6c34\u8868\u9762\u3001\u30b9\u30de\u30fc\u30c8\u8868\u9762\u3001\u306b\u3064\u3044\u3066\u306e\u6700\u8fd1\u306e\u60c5\u5831\u3092\u307e\u3068\u3081\u3066\u3044\u308b\u3002\u3055\u3089\u306b\u8d85\u64a5\u6cb9\u6027\u8868\u9762\u306e\u5fdc\u7528\u3001\u6c34\u4e2d\u3067\u306e\u8d85\u64a5\u6cb9\u8868\u9762\u306b\u3064\u3044\u3066\u8a00\u53ca\u3057\u3066\u3044\u308b\u3002\u4f46\u3057\u3001\u6c34\u4e2d\u3067\u306e\u8d85\u64a5\u6cb9\u6027\u8868\u9762\u306b\u306f\u30d5\u30c3\u7d20\u306f\u95a2\u4e0e\u305b\u305a\u3001\u9b5a\u306e\u9c57\u306e\u3088\u3046\u306a\u89aa\u6c34\u6027\u8868\u9762\u304c\u8ff0\u3079\u3089\u308c\u3066\u3044\u308b\u306e\u3067\u3053\u3053\u3067\u306f\u7701\u7565\u3059\u308b\u3002<\/p>\n

\u7406\u8ad6\u7684\u306a\u80cc\u666f\u3068\u3057\u3066\u306f\u3001\u7c97\u3044\u8868\u9762\u3092\u8003\u616e\u306b\u5165\u308c\u305fWenzel\u30e2\u30c7\u30eb\u3001Cassie-Baxter\u30e2\u30c7\u30eb\u304c\u3042\u308a\u3001\u8d85\u64a5\u6c34\u6027\u3092\u8aac\u660e\u3057\u3066\u304d\u305f\u304c\u3001\u8d85\u64a5\u6cb9\u6027\uff08\u6709\u6a5f\u6db2\u4f53\u306e\u63a5\u89e6\u89d2150\u2103\u4ee5\u4e0a\uff09\u306b\u3064\u3044\u3066\u306f\u3001\u6700\u8fd1\u306e\u4fee\u6b63Cassie-Baxter\u30e2\u30c7\u30eb\u304c\u3042\u308b\u3002\u3053\u308c\u306f\u3001Wenzel\u30e2\u30c7\u30eb\u306e\u8003\u3048\u65b9\u3092\u53d6\u308a\u5165\u308c\u3001\u3055\u3089\u306b\u7c97\u8868\u9762\u69cb\u9020\u306e\u30c7\u30b6\u30a4\u30f3\u3092\u91cd\u8981\u8996\u3057\u305f\u3082\u306e\u3067\u3001\u751f\u7269\u306b\u30d2\u30f3\u30c8\u3092\u5f97\u305f\u56f31\u306e\u30aa\u30fc\u30d0\u30fc\u30cf\u30f3\u30b0\u69cb\u9020(\u8d64\u306e\u90e8\u5206\u304c\u56fa\u4f53\u69cb\u9020\u3001\u9752\u306e\u90e8\u5206\u304c\u6db2\u4f53)\u3084\u56f32\u306e\u30ea\u30a8\u30f3\u30c8\u30e9\u30f3\u30c8\u69cb\u9020\u304c\u63d0\u793a\u3055\u308c\u3066\u3044\u308b\u3002\u8d85\u64a5\u6cb9\u6027\u306e\u5834\u5408\u3001\u30aa\u30a4\u30eb\u3088\u308a\u3082\u4f4e\u3044\u8868\u9762\u5f35\u529b\u304c\u5fc5\u8981\u3067\u3001\u30d5\u30c3\u7d20\u7cfb\u30dd\u30ea\u30de\u30fc\u306e\u307f\u304c\u3053\u306e\u8981\u6c42\u3092\u6e80\u305f\u3059\u3002
\n\"FT1\"<\/p>\n

\u6b21\u3044\u3067\u3001\u8d85\u64a5\u6cb9\u30fb\u64a5\u6c34\u8868\u9762\u306b\u5bfe\u3059\u308b\u30a2\u30d7\u30ed\u30fc\u30c1\u306b\u3064\u3044\u306613\u306e\u65b9\u6cd5\u3092\u8ff0\u3079\u3066\u3044\u308b\u3002<\/p>\n

(1)\u30bb\u30eb\u30ed\u30fc\u30b9\u306b\u539f\u5b50\u79fb\u52d5\u30e9\u30b8\u30ab\u30eb\u91cd\u5408\uff08ATRP\uff09\u3067\u30b0\u30ea\u30b7\u30b8\u30eb\u30e1\u30bf\u30af\u30ea\u30ec\u30fc\u30c8\u3092\u91cd\u5408\u3057\u3001\u3055\u3089\u306bC7F15COCl\u3092\u51e6\u7406\u3057\u305f\u7cfb\u3067\u30d2\u30de\u30ef\u30ea\u6cb9\u306e\u63a5\u89e6\u89d2\u304c144\u5ea6\u3068\u9ad8\u3044\u64a5\u6cb9\u6027\u3092\u793a\u3057\u305f\u3002
\n(2)PMMA\u3068\u672b\u7aef\u30d5\u30c3\u7d20\u30a6\u30ec\u30bf\u30f3\u30dd\u30ea\u30de\u30fc\u3092\u4e00\u6bb5\u6ce8\u578b\u306b\u3088\u308a\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u3057\u305f\u3002\u751f\u6210\u30d5\u30a3\u30eb\u30e0\u306f\u30df\u30af\u30ed\u306e\u7d50\u7bc0\u304b\u3089\u6210\u308a\u7acb\u3063\u3066\u3044\u3066\u3001\u8d85\u64a5\u6c34\u30fb\u8d85\u64a5\u6cb9\u6027\u3092\u793a\u3057\u305f\u3002
\n(3)\u30ca\u30ce\u591a\u5b54\u6027\u30dd\u30ea(3,4\u2010\u30a8\u30c1\u30ec\u30f3\u30b8\u30aa\u30ad\u30b7\u30c1\u30aa\u30d5\u30a7\u30f3)\u3092CuCl2\u306b\u3088\u308bCVD\u30d7\u30ed\u30bb\u30b9\u3067\u4f5c\u88fd\u3057\u8d85\u64a5\u6c34\u30fb\u64a5\u6cb9\u6027\u3092\u9054\u6210\u3002
\n(4)\u591a\u9762\u30a2\u30eb\u30df\u30ca\u30ca\u30ce\u30ef\u30a4\u30e4\u30fc\u3092\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u30b7\u30e9\u30f3\uff08FAS)\u306e\u30d8\u30ad\u30b5\u30f3\u6eb6\u6db2\u306b\u30c7\u30a3\u30c3\u30d4\u30f3\u30b0\u3067\u9054\u6210\u3002
\n(5)\u30dd\u30ea(\u03b5-\u30ab\u30d7\u30ed\u30e9\u30af\u30c8\u30f3)\u3092\u30a8\u30ec\u30af\u30c8\u30ed\u30b9\u30d4\u30cb\u30f3\u30b0\u3057\u305f\u5f8c\u306b\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u30a8\u30c1\u30eb\u30e1\u30bf\u30af\u30ea\u30ec\u30fc\u30c8(PFEEMA)\u3092\u30b3\u30fc\u30c8\u3057\u3066\u9054\u6210\u3002
\n(6)\u91d1\u30a2\u30b7\u30b9\u30c8\u7121\u96fb\u89e3\u30a8\u30c3\u30c1\u30f3\u30b0\u306b\u3088\u308a\u591a\u5b54\u8cea\u30b7\u30ea\u30b3\u30f3\u30d5\u30a3\u30eb\u30e0\u3092\u4f5c\u88fd\u3057\u3001\u30d5\u30c3\u7d20\u7cfb\u30dd\u30ea\u30de\u30fc\u3092\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u3057\u3066\u9054\u6210\u3002
\n(7)\u4ea4\u4e92\u7a4d\u5c64\u6cd5\uff08LBL\uff09\u306b\u3088\u308a\u30b7\u30ea\u30ab\u30ca\u30ce\u7c92\u5b50\u3084\u30dd\u30ea\u30b9\u30c1\u30ec\u30f3\u30ca\u30ce\u7c92\u5b50\u3092\u4f5c\u88fd\u3057\u3001\u30d5\u30eb\u30aa\u30ed\u30ab\u30fc\u30dc\u30f3\u5206\u5b50\u3067\u8868\u9762\u6539\u8cea\u3002
\n(8)\u30dd\u30ea[2-(\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30aa\u30af\u30c1\u30eb)\u30a8\u30c1\u30eb\u30e1\u30bf\u30af\u30ea\u30ec\u30fc\u30c8]\uff08PFOEMA\uff09\u3068\u30dd\u30ea[3-(\u30c8\u30ea\u30a4\u30bd\u30d7\u30ed\u30d4\u30eb\u30b7\u30ea\u30eb)\u30d7\u30ed\u30d4\u30eb\u30e1\u30bf\u30af\u30ea\u30ec\u30fc\u30c8\uff08PIPSMA\uff09\u3068\u306e\u30d6\u30ed\u30c3\u30af\u5171\u91cd\u5408\u4f53(PFOEMA-\uff42-PIPSMA)\u3092\u4f5c\u88fd\u3057\u3001\u30be\u30eb\u30b2\u30eb\u6cd5\u3067\u30c6\u30c8\u30e9\u30a8\u30c8\u30ad\u30b7\u30b7\u30e9\u30f3\u304b\u3089\u5408\u6210\u3057\u305f\u30b7\u30ea\u30ab\u7c92\u5b50\u306b\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u3002
\n(9)\u5782\u76f4\u914d\u5411\u30ab\u30fc\u30dc\u30f3\u30ca\u30ce\u30c1\u30e5\u30fc\u30d6\u3092\u77f3\u82f1\u30ac\u30e9\u30b9\u4e0a\u3067\u91d1\u5c5e\u30d5\u30bf\u30ed\u30b7\u30a2\u30cb\u30f3\u3092\u71b1\u5206\u89e3\u3055\u305b\u3066\u4f5c\u88fd\u3057\u3001\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u30b7\u30e9\u30f3\u3092\u30b3\u30fc\u30c8\u3002
\n(10)\u672b\u7aef\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u57fa\u3001\u30d3\u30d5\u30a7\u30cb\u30ec\u30f3\u542b\u6709\u30d3\u30cb\u30eb\u30c8\u30ea\u30e1\u30c8\u30ad\u30b7\u30b7\u30e9\u30f3\u30aa\u30ea\u30b4\u30de\u30fc\u30ca\u30ce\u30b3\u30f3\u30dd\u30b8\u30c3\u30c8\u3092\u30be\u30eb\u30b2\u30eb\u6cd5\u3067\u4f5c\u88fd\u3057\u3066\u9054\u6210\u3002
\n(11)\u4e9c\u925b\u3001\u30a2\u30eb\u30df\u30cb\u30a6\u30e0\u3001\u9244\u3001\u30cb\u30c3\u30b1\u30eb\u3084\u4e9c\u925b-\u9244\u5408\u91d1\u3092\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30ab\u30eb\u30dc\u30f3\u9178\u306e\u30a8\u30bf\u30ce\u30fc\u30eb\u6eb6\u6db2\u306b\u6d78\u6f2c\u3057\u3066\u9054\u6210\u3002
\n(12)\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30aa\u30af\u30bf\u30f3\u9178\u9285\u306e\u61f8\u6fc1\u6db2\u3092\u30b9\u30d7\u30ec\u30fc\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u3002
\n(13)\u30ac\u30e9\u30b9\u306b\u874b\u71ed\u306e\u7164\u3092\u30c7\u30dd\u30b8\u30c3\u30c8\u3055\u305b\u3066\u92f3\u578b\u3092\u4f5c\u308a\u3001\u305d\u308c\u306b\u30d5\u30eb\u30aa\u30ed\u30ab\u30fc\u30dc\u30f3\u3092CVD\u3067\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u3059\u308b\u3002<\/p>\n

\u6b21\u3044\u3067\u3001\u64a5\u6cb9\u6027\u2015\u89aa\u6c34\u6027\u8868\u9762\u306b\u3064\u3044\u3066\u3044\u304f\u3064\u304b\u306e\u65b9\u6cd5\u3092\u5217\u6319\u3057\u3066\u3044\u308b\u3002<\/p>\n

(1)\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u672b\u7aef\u306e\u30dd\u30ea\u30a8\u30c1\u30ec\u30f3\u30b0\u30ea\u30b3\u30fc\u30eb\u3092\u5237\u6bdb\u3067\u5857\u308b\u3002
\n(2)\u9ad8\u5206\u5b50\u96fb\u89e3\u8cea\u3068\u30d5\u30c3\u7d20\u7cfb\u754c\u9762\u6d3b\u6027\u5264\u306e\u932f\u4f53\u3001\u4f8b\u3048\u3070\u30a2\u30af\u30ea\u30eb\u9178\u30d7\u30e9\u30ba\u30de\u30dd\u30ea\u30de\u30fc\u306e\u8584\u819c\u306b\u30d5\u30c3\u7d20\u7cfb\u30ab\u30c1\u30aa\u30f3\u6027\u754c\u9762\u6d3b\u6027\u5264\u3067\u932f\u5f62\u6210\u3055\u305b\u3066\u9054\u6210\u3002
\n(3)\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u5316\u30d5\u30ea\u30c3\u30d7\u30d5\u30ed\u30c3\u30d7\u578b\u30b7\u30e9\u30f3\u30ab\u30c3\u30d7\u30ea\u30f3\u30b0\u5264\u3092\u30ac\u30e9\u30b9\u8868\u9762\u306b\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u3002\u3053\u306e\u30b7\u30e9\u30f3\u30ab\u30c3\u30d7\u30ea\u30f3\u30b0\u5264\u306f\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ab\u30ce\u30a4\u30eb\u30d1\u30fc\u30aa\u30ad\u30b5\u30a4\u30c9\u3068\u30c8\u30ea\u30e1\u30c8\u30ad\u30b7\u30d3\u30cb\u30eb\u30b7\u30e9\u30f3\u304a\u3088\u3073\u30a2\u30af\u30ea\u30ed\u30a4\u30eb\u30e2\u30eb\u30d5\u30a9\u30ea\u30f3\u3068\u306e\u53cd\u5fdc\u306b\u3088\u308a\u4f5c\u88fd\u3059\u308b\u3002
\n(4)\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30aa\u30af\u30bf\u30f3\u9178\u30a4\u30aa\u30f3-\u30dd\u30ea(\u30b8\u30a2\u30ea\u30eb\u30b8\u30e1\u30c1\u30eb\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\u30af\u30ed\u30e9\u30a4\u30c9)\u3092\u30ca\u30ce\u7c92\u5b50\u30dd\u30ea\u30de\u30fc\u306b\u30b9\u30d7\u30ec\u30fc\u30b3\u30fc\u30c6\u30a3\u30f3\u30b0\u3059\u308b\u3002
\n(5)\u30dd\u30ea\u30b9\u30c1\u30ec\u30f3-\u30e2\u30f3\u30e2\u30ea\u30ed\u30ca\u30a4\u30c8\u3092\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30dd\u30ea\u30a8\u30fc\u30c6\u30eb\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\u5869\u3067\u51e6\u7406\u3057\u305f\u3082\u306e\u3092\u30b9\u30d4\u30f3\u30b3\u30fc\u30c8\u3059\u308b\u3002<\/p>\n

\u3055\u3089\u306b\u3001\u30b9\u30de\u30fc\u30c8\u8868\u9762\u306b\u3064\u3044\u3066\u8ff0\u3079\u3066\u3044\u308b\u3002\u30b9\u30de\u30fc\u30c8\u8868\u9762\u3068\u306f\u53ef\u9006\u7684\u8d85\u64a5\u6cb9\/\u8d85\u89aa\u6cb9\u6027\u304a\u3088\u3073\u81ea\u5df1\u4fee\u5fa9\u6027\u306e\u3053\u3068\u3067\u3001\u524d\u8005\u306b\u3064\u3044\u3066\u306f\u4e0b\u8a18\u306e7\u65b9\u6cd5\u304c\u6319\u3052\u3089\u308c\u3066\u3044\u308b\u3002<\/p>\n

(1)\u30a2\u30eb\u30df\u30cb\u30a6\u30e0\u8868\u9762\u3067\u306e\u30ab\u30a6\u30f3\u30bf\u30fc\u30a4\u30aa\u30f3\u3092\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30aa\u30af\u30bf\u30f3\u9178\u30a4\u30aa\u30f3(PFO) \u3068\u30c9\u30c7\u30b7\u30eb\u30b9\u30eb\u30db\u30f3\u9178\u30ca\u30c8\u30ea\u30a6\u30e0(DYS)\u306e\u9023\u7d9a\u7684\u306b\u4ea4\u63db\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u9054\u6210\u3002\u5373\u3061PFO\u3068DYS\u3092\u4ea4\u63db\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u30d8\u30ad\u30b5\u30c7\u30ab\u30f3\u306e\u63a5\u89e6\u89d2\u304c160\u5ea6(\u8d85\u64a5\u6cb9\uff09\u30680\u5ea6(\u8d85\u89aa\u6cb9\uff09\u3068\u5909\u308f\u308b\u3002
\n\"FT2\"
\n(2)\u30ca\u30ce\u30cd\u30a4\u30eb\u3042\u308b\u3044\u306f\u30cf\u30cb\u30ab\u30e0\u69cb\u9020\u306e\u8d85\u64a5\u6cb9\u4f1d\u5c0e\u6027\u30b3\u30a2\u3068\u6db2\u4f53\u3068\u306e\u9593\u306b\u96fb\u5727\u3092\u304b\u3051\u308b\u3002
\n(3)\u8d85\u64a5\u6cb9TiO2\u306bUV\u7167\u5c04
\n(4)\u30cb\u30c3\u30b1\u30eb\u30df\u30af\u30ed\u30cd\u30a4\u30eb\u3092\u8d85\u64a5\u6cb9\u51e6\u7406\u3057\u3066\u78c1\u5834\u3092\u304b\u3051\u308b\u3002
\n(5)\u9285\u8868\u9762\u3092\u30d5\u30c3\u7d20\u5316\u3057\u3066\u8d85\u64a5\u6cb9\u8868\u9762\u3092\u4f5c\u88fd\u5f8c\u3001\u30d7\u30e9\u30ba\u30de\u51e6\u7406\u3059\u308b\u3002
\n(6)\u8d85\u64a5\u6cb9\u8868\u9762\u3092\u30a8\u30c3\u30c1\u30f3\u30b0\u306a\u3069\u3067\u5f62\u614b\u3092\u5909\u3048\u308b\u3002
\n(7)\u30dd\u30ea\u30a8\u30b9\u30c6\u30eb\u5e03\u309210%\u30d5\u30eb\u30aa\u30ed\u30c7\u30b7\u30eb\u30dd\u30ea\u30d8\u30c9\u30e9\u30eb\u30aa\u30ea\u30b4\u30e1\u30ea\u30c3\u30af\u30b7\u30eb\u30bb\u30b9\u30ad\u30aa\u30ad\u30b5\u30f3(FD-POSS)\/90%\u30dd\u30ea\u30a8\u30c1\u30eb\u30e1\u30bf\u30af\u30ea\u30ec\u30fc\u30c8\uff08PEMA\uff09\u306b\u6d78\u6f2c\u3001PEMA\u306eTg\u4ee5\u4e0a\u306e\u6e29\u5ea6\u306b\u3059\u308b\u3002\u5f8c\u8005\u306e\u81ea\u5df1\u4fee\u5fa9\u6027\u306b\u3064\u3044\u3066\u306f\u3001FD-POSS\/\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u30b7\u30e9\u30f3\u3092\u30b3\u30fc\u30c8\u3057\u305f\u8868\u9762\u3092UV\u7167\u5c04\u3057\u305f\u308a\u3001\u6d17\u6fef\u3057\u305f\u308a\u3001\u6469\u64e6\u3059\u308b\u3068\u8d85\u64a5\u6cb9\u6027\u304c\u4f4e\u4e0b\u3059\u308b\u304c\u3001\u52a0\u71b1\u3059\u308b\u3053\u3068\u306b\u3088\u308aFD-POSS\u304c\u79fb\u52d5\u3057\u3066\u5143\u306b\u623b\u308b\u3053\u3068\u304c\u8ff0\u3079\u3089\u308c\u3066\u3044\u308b\u3002\u305d\u306e\u5834\u5408\u3001\u6975\u6027\u30b0\u30eb\u30fc\u30d7\u304c\u5c0e\u5165\u3055\u308c\u3066\u8d85\u64a5\u6cb9\u6027\u304c\u4f4e\u4e0b\u3059\u308b\u3068\u3057\u3066\u3044\u308b\u3002<\/p>\n

\u6b21\u3044\u3067\u3001\u8d85\u64a5\u6cb9\u6027\u8868\u9762\u306e\u5fdc\u7528\u306b\u3064\u3044\u3066\u8a00\u53ca\u3057\u3066\u3044\u308b\u3002\u4ee5\u4e0b\u306b\u5217\u6319\u3059\u308b\u3002\u307e\u305a\u306f\u3001\u8d85\u64a5\u6c34\u30fb\u64a5\u6cb9\u8868\u9762\u306e\u5fdc\u7528\u4f8b\u3001(1)\u9632\u30ab\u30d3\uff1aC6F13C2H4Si(OET)3\/\u9280\u30ca\u30ce\u7c92\u5b50\u51e6\u7406\u3057\u305f\u7dbf\u5e03(2)\u53cd\u5c04\u9632\u6b62\uff1aFAS\u3067\u51e6\u7406\u3057\u305fSiO2\u30d5\u30a3\u30eb\u30e0(3)\u9632\u9306\uff1aPFOEMA-\uff42-PIPSMA\u3092\u30b3\u30fc\u30c8\u3057\u305fSiO2(4)\u6c34\u3084\u6cb9\u306e\u4e0a\u3092\u79fb\u52d5\u3067\u304d\u308b\u30c7\u30d0\u30a4\u30b9\uff1a\u30d5\u30c3\u7d20\u5316\u30ca\u30ce\u69cb\u9020\u30a8\u30a2\u30ed\u30b2\u30eb(5)\u96fb\u754c\u52b9\u679c\u30c8\u30e9\u30f3\u30b8\u30b9\u30bf\uff08FET\uff09\uff1a\u8d85\u64a5\u6c34\u64a5\u6cb9\u51e6\u7406\u3057\u305f\u91d1\u30ca\u30ce\u7c92\u5b50(6)\u9632\u71b1\uff1a\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30dd\u30ea\u30a8\u30fc\u30c6\u30eb\u51e6\u7406\u30bb\u30e9\u30df\u30c3\u30af\u30b9(7)\u30aa\u30a4\u30eb\u30ad\u30e3\u30d7\u30c1\u30e3\u30fc\uff1a\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30c7\u30b7\u30eb\u30c8\u30ea\u30af\u30ed\u30ed\u30b7\u30e9\u30f3\u3067\u51e6\u7406\u3057\u305f\u8868\u9762(8)\u30aa\u30a4\u30eb\u8f38\u9001\uff1aCu(OH)2\u30ca\u30ce\u69cb\u9020\u8868\u9762\u306b\u30d1\u30d5\u30eb\u30aa\u30ed\u30c1\u30aa\u30ec\u30fc\u30c8\u3092\u51e6\u7406(9)\u30bb\u30eb\u30d5\u30af\u30ea\u30fc\u30cb\u30f3\u30b0\uff1a\u30d5\u30c3\u7d20\u5316\u81ea\u5df1\u7d44\u7e54\u5316\u5358\u5c64\u3092\u6709\u3059\u308b\u30b7\u30ea\u30b3\u30f3\u3002<\/p>\n

\u6b21\u3044\u3067\u64a5\u6cb9\u30fb\u89aa\u6c34\u8868\u9762\u306e\u5fdc\u7528\u4f8b\u306b\u3064\u3044\u3066\u306f\u3001(1)\u9632\u30ab\u30d3(2)\u9632\u9727\/\u30bb\u30eb\u30d5\u30af\u30ea\u30fc\u30cb\u30f3\u30b0(3)\u6c34\/\u30aa\u30a4\u30eb\u5206\u96e2\u306e3\u4f8b\u3092\u6319\u3052\u3066\u3044\u308b\u3002<\/p>\n

\u6700\u5f8c\u306b\u3001\u3053\u3046\u3057\u305f\u8d85\u64a5\u6cb9\u8868\u9762\u306e\u4f5c\u88fd\u306f\u3001\u6700\u521d\u306f\u751f\u4f53\u306e\u6a21\u5023\u3067\u3042\u3063\u305f\u304c\u3001\u73fe\u5728\u3067\u306f\u305d\u308c\u3092\u8d85\u3048\u305f\u72b6\u6cc1\u306b\u3042\u308b\u3068\u3057\u3066\u3044\u308b\u3002\u305d\u3057\u3066\u3001\u30b9\u30de\u30fc\u30c8\u8868\u9762\u304c\u6700\u3082\u8208\u5473\u6df1\u304f\u3001\u30bb\u30f3\u30b5\u30fc\u3001\u30c7\u30d0\u30a4\u30b9\u3001\u81ea\u5df1\u4fee\u5fa9\u7269\u8cea\u306a\u3069\u3001\u5e45\u5e83\u3044\u5fdc\u7528\u30dd\u30c6\u30f3\u30b7\u30e3\u30eb\u304c\u3042\u308b\u3068\u7d50\u3093\u3067\u3044\u308b\u3002<\/p>\n

3\u3001\u305d\u306e\u4ed6\u306e\u6700\u8fd1\u306e\u6587\u732e\u304b\u3089
\nBormashenko\u3089\u306f\u3001LDPE\u30d5\u30a3\u30eb\u30e0\u306e\u8868\u9762\u3092\u30cf\u30b9\u306e\u8449\u306b\u4f3c\u305b\u305f\u30a8\u30f3\u30dc\u30b9\u52a0\u5de5\u5f8c\u306bCF4\u30d7\u30e9\u30ba\u30de\u51e6\u7406\u3057\u3066\u3001\u6c34\u306e\u63a5\u89e6\u89d2180\u5ea6\u3001\u30b8\u30e1\u30c1\u30eb\u30b9\u30eb\u30d5\u30a9\u30ad\u30b5\u30a4\u30c9142\u5ea6\u3001CH2I2143\u5ea6\u306e\u8d85\u64a5\u6c34\u30fb\u9ad8\u64a5\u6cb9\u6027\u3092\u5f97\u3066\u3044\u308b\u30022)
\n\u307e\u305f\u3001\u767d\u9ce5\u3089\u306f\u3001TiO2\u30ca\u30ce\u7c92\u5b50\u3092\u30a2\u30af\u30ea\u30eb\u9178\u3001\u3055\u3089\u306b\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u30e1\u30bf\u30af\u30ea\u30ec\u30fc\u30c8\u306e\u5206\u6563\u6c34\u6eb6\u6db2\u306e\u30aa\u30fc\u30eb\u6c34\u7cfb\u3067\u51e6\u7406\u3057\u3001\u30ac\u30e9\u30b9\u306b\u5857\u5e03\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u30d8\u30ad\u30b5\u30c7\u30ab\u30f3\u306e\u63a5\u89e6\u89d2145\u5ea6\u306e\u9ad8\u64a5\u6cb9\u8868\u9762\u3092\u5f97\u305f\u30023)
\n\u3055\u3089\u306b\u3001McKinley\u3089\u306f\u3001C8F17C2H4\u57fa\u3067\u4fee\u98fe\u3057\u305f\u30dd\u30ea\u30d8\u30c9\u30e9\u30eb\u30aa\u30ea\u30b4\u30e1\u30ea\u30c3\u30af\u30b7\u30eb\u30bb\u30b9\u30ad\u30aa\u30ad\u30b5\u30f3(POSS)\u3092\u30b9\u30d7\u30ec\u30a4\u30b3\u30fc\u30c8\u3057\u3066\u3001\u8868\u9762\u306e\u30df\u30af\u30ed\u69cb\u9020\u3092\u5909\u3048\u3001\u8d85\u64a5\u6cb9\u8868\u9762(\u30b8\u30e1\u30c1\u30eb\u30b9\u30eb\u30d5\u30a9\u30aa\u30ad\u30b5\u30a4\u30c9\u3001\u30d8\u30ad\u30b5\u30c7\u30ab\u30f3)\u3092\u9054\u6210\u3057\u3066\u3044\u308b\u30024)<\/p>\n

4\u3001\u304a\u308f\u308a\u306b
\n\u8d85\u64a5\u6cb9\u6027\u306b\u95a2\u3059\u308b\u4e2d\u56fd\u306e\u512a\u308c\u305f\u7dcf\u8aac\u3092\u4e2d\u5fc3\u306b\u6700\u8fd1\u306e\u6587\u732e\u3092\u307e\u3068\u3081\u3066\u307f\u305f\u3002\u5148\u306b\u3082\u8ff0\u3079\u305f\u304c\u3001\u8d85\u64a5\u6cb9\u6027\u306f\u30d5\u30c3\u7d20\u7cfb\u3067\u306a\u3044\u3068\u9054\u6210\u3067\u304d\u306a\u3044\u3002\u305d\u3057\u3066\u3001\u8d85\u64a5\u6c34\u6027\u3088\u308a\u3082\u3055\u3089\u306b\u8208\u5473\u6df1\u3044\u73fe\u8c61\u3067\u3042\u308a\u3001\u4eca\u5f8c\u306e\u5fdc\u7528\u306b\u671f\u5f85\u304c\u304b\u304b\u308b\u3002\u305f\u3060\u3001\u8d85\u64a5\u6c34\u6027\u8868\u9762\u306b\u304a\u3044\u3066\u5fdc\u7528\u5c55\u958b\u304c\u9045\u308c\u3066\u3044\u308b\u8010\u4e45\u6027\u306b\u3064\u3044\u3066\u306f\u8d85\u64a5\u6cb9\u6027\u306b\u3082\u540c\u3058\u3053\u3068\u3060\u3068\u601d\u3046\u3002\u7dcf\u8aac\u3067\u306f\u3001\u81ea\u5df1\u4fee\u5fa9\u6027\u3084\u30bb\u30eb\u30d5\u30af\u30ea\u30fc\u30cb\u30f3\u30b0\u304c\u8ff0\u3079\u3089\u308c\u3066\u3044\u308b\u304c\u3001\u3053\u308c\u304c\u9054\u6210\u3067\u304d\u308c\u3070\u3001\u8010\u4e45\u6027\u306e\u8ab2\u984c\u89e3\u6c7a\u306b\u3064\u306a\u304c\u308b\u306e\u3067\u306f\u306a\u3044\u304b\u3068\u8003\u3048\u3066\u3044\u308b\u3002<\/p>\n

\u6587\u732e
\n1) Kesong Liu et al Progress in Materials Science 58\uff082013\uff09 503-564
\n 2) Edward Bormashenko et al Applied Surface Science 270(2013) 98-103
\n 3) Seimei Shiratori et al Applied Surface Science 263(2012) 8-13
\n 4) Gareth H. McKinley et al Polymer 52(2011) 3209-3218 <\/p>\n","protected":false},"excerpt":{"rendered":"

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