{"id":414,"date":"2012-05-31T11:22:41","date_gmt":"2012-05-31T02:22:41","guid":{"rendered":"http:\/\/ft-net.co.jp\/topic\/?p=414"},"modified":"2013-11-12T15:51:02","modified_gmt":"2013-11-12T06:51:02","slug":"%e3%80%8c%e5%90%ab%e3%83%95%e3%83%83%e7%b4%a0%e3%83%81%e3%82%aa%e3%83%bc%e3%83%ab%e8%87%aa%e5%b7%b1%e9%85%8d%e5%90%91%e5%8d%98%e5%88%86%e5%ad%90%e5%b1%a4%e3%80%8d","status":"publish","type":"post","link":"https:\/\/ft-net.co.jp\/topic\/?p=414","title":{"rendered":"\u300c\u542b\u30d5\u30c3\u7d20\u30c1\u30aa\u30fc\u30eb\u81ea\u5df1\u914d\u5411\u5358\u5206\u5b50\u5c64\u300d"},"content":{"rendered":"

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\nhttp:\/\/www.daikin.co.jp\/chm\/products\/fine\/backnum\/201205\/#topic01<\/p>\n

1\u3001\u306f\u3058\u3081\u306b
\n\u81ea\u5df1\u914d\u5411\u5358\u5206\u5b50\u5c64(SAM)\u306b\u3064\u3044\u3066\u306f\u3001\u6700\u8fd1\u76db\u3093\u306b\u7814\u7a76\u3055\u308c\u3066\u3044\u308b\u3002\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u57fa\u3092\u6709\u3059\u308b\u5316\u5408\u7269\u306fSAM\u3092\u4f5c\u88fd\u3057\u6613\u304f\u3001\u7279\u7570\u306a\u6a5f\u80fd\u3092\u767a\u63ee\u3059\u308b\u3002\u305d\u306e\u4e2d\u3067\u3001\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30eb\u57fa\u3092\u6709\u3059\u308b\u30c1\u30aa\u30fc\u30eb\u306eSAM\u306b\u3064\u3044\u3066\u3001\u6700\u65b0\u306e\u6587\u732e\u3092\u7d39\u4ecb\u3059\u308b\u3002 <\/p>\n

2\u3001SAM\u306b\u3088\u308b\u30da\u30f3\u30bf\u30bb\u30f3\u6709\u6a5f\u96fb\u754c\u52b9\u679c\u30c8\u30e9\u30f3\u30b8\u30b9\u30bf\u306e\u9280\u30bd\u30fc\u30b9\/\u30c9\u30ec\u30a4\u30f3\u96fb\u6975\u306e\u6539\u8cea1)
\n\u6709\u6a5f\u8584\u819c\u30c8\u30e9\u30f3\u30b8\u30b9\u30bf\u30fc(OTFTs)\u306f\u3001\u4f4e\u30b3\u30b9\u30c8\u3001\u6613\u6210\u5f62\u6027\u3001\u67d4\u8edf\u6027\u306a\u3069\u306e\u5229\u70b9\u306b\u3088\u308a\u3001\u6709\u6a5fLED\u306e\u99c6\u52d5\u56de\u8def\u3001\u7121\u7ddaID\u30bf\u30b0\u3084\u30bb\u30f3\u30b5\u30fc\u306a\u3069\u3068\u3057\u3066\u671f\u5f85\u3055\u308c\u3066\u3044\u308b\u3002\u96fb\u6975\u3068\u306e\u30dc\u30c8\u30e0\u63a5\u89e6\u306f\u96c6\u7a4d\u56de\u8def\u306b\u9069\u3057\u3066\u3044\u308b\u3002\u30c7\u30d0\u30a4\u30b9\u306e\u6027\u80fd\u306f\u3001\u96fb\u6975\u3068\u6709\u6a5f\u534a\u5c0e\u4f53\u3068\u306e\u5883\u754c\u9762\u306b\u4f9d\u5b58\u3059\u308b\u3002\u3064\u307e\u308a\u3001\u6709\u6a5f\u534a\u5c0e\u4f53\u306eHOMO\u30ec\u30d9\u30eb\u3068\u96fb\u6975\u306e\u4ed5\u4e8b\u95a2\u6570\u306e\u9593\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u5dee\u304c\u5927\u304d\u304f\u5f71\u97ff\u3059\u308b\u3002\u91d1\u96fb\u6975\u306e\u4ed5\u4e8b\u95a2\u6570\u306f\u7d045.1eV\u3067\u307b\u3068\u3093\u3069\u306ep-\u30bf\u30a4\u30d7\u306e\u6709\u6a5f\u534a\u5c0e\u4f53\u306eHOMO\u30a8\u30cd\u30eb\u30ae\u30fc\u30ec\u30d9\u30eb\u3068\u30de\u30c3\u30c1\u3059\u308b\u306e\u3067\u3088\u304f\u4f7f\u308f\u308c\u3066\u3044\u308b\u3002\u9280\u96fb\u6975\u306f\u91d1\u306b\u6bd4\u3079\u308b\u3068\u30b3\u30b9\u30c8\u306f\u5b89\u3044\u304c\u3001\u305d\u306e\u4ed5\u4e8b\u95a2\u6570\u306f\u6709\u6a5f\u534a\u5c0e\u4f53\u3068\u30de\u30c3\u30c1\u3057\u306b\u304f\u3044\u3002\u3057\u304b\u3057\u3001\u305d\u306e\u8868\u9762\u306b\u81ea\u5df1\u7d44\u7e54\u5316\u5358\u5206\u5b50\u5c64\uff08SAMs)\u3092\u5f62\u6210\u3055\u305b\u308b\u3068\u30de\u30c3\u30c1\u3059\u308b\u3088\u3046\u306b\u306a\u308b\u3053\u3068\u304c\u5206\u304b\u3063\u3066\u304d\u305f\u3002\u3053\u3053\u3067\u306f\u30dc\u30c8\u30e0\u63a5\u89e6\u9280\u96fb\u6975OTFTs\u306b\u304a\u3044\u3066\u3001C8F17C2H4SH(FDT)\u3068C10H21SH(HDT))\u3068\u306e2\u6210\u5206\u7cfbSAMs\u3092\u9280\u96fb\u6975\u306b\u5f62\u6210\u3055\u305b\u308b\u3053\u3068\u306b\u3088\u308a\u91d1\u96fb\u6975\u3088\u308a\u6027\u80fd\u304c\u5411\u4e0a\u3057\u305f\u3053\u3068\u304c\u5831\u544a\u3055\u308c\u3066\u3044\u308b\u3002
\n\u9280\u96fb\u6975\u8868\u9762\u306bFDT\/HDT SAMs\u3092\u5f62\u6210\u3055\u305b\u305f\u3068\u304d\u306e\u4ed5\u4e8b\u95a2\u6570\u3092Fig.1\u306b\u793a\u3059\u3002\u9280\u96fb\u6975\u306e\u4ed5\u4e8b\u95a2\u6570\u306f4.26eV\u3067\u3042\u308a\u3001Fig.1\u3088\u308a\u3001HDT\u306e\u307f\u306eSAM\u3092\u5f62\u6210\u3055\u305b\u305f\u3068\u304d\u306f4.3eV\u3067\u3042\u3063\u305f\u3002\u307e\u305f\u3001FDT\u306e\u307f\u306eSAM\u306e\u5834\u5408\u306f6.0eV\u3067\u3042\u308a\u3001FDT\u3068HDT\u3068\u306e\u6bd4\u7387\u3092\u5909\u3048\u3066\u3044\u304f\u3068\u4ed5\u4e8b\u95a2\u6570\u306f\u305d\u306e\u9593\u306e\u5024\u3092\u793a\u3057\u305f\u3002\u672c\u7814\u7a76\u306e\u5834\u5408\u306eTFT\u306e\u6d3b\u6027\u5c64\u306f\u7d045.2eV\u306e\u30a4\u30aa\u30f3\u5316\u30dd\u30c6\u30f3\u30b7\u30e3\u30eb\u3092\u6709\u3057\u3066\u3044\u308b\u306e\u3067\u3001FDT\/HDT\u6bd43\/1\u304c\u9280\u96fb\u6975\u6539\u8cea\u3057\u3066\u30da\u30f3\u30bf\u30bb\u30f3\u306eLUMO\u306bFermi\u30ec\u30d9\u30eb\u3092\u5408\u308f\u305b\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3053\u3068\u304c\u5206\u304b\u3063\u305f\u3002
\n\u307e\u305f\u3001\u30da\u30f3\u30bf\u30bb\u30f3TFT\u306e\u30c9\u30ec\u30a4\u30f3\u96fb\u6d41-\u30c9\u30ec\u30a4\u30f3\u96fb\u5727\u7279\u6027\u306b\u3064\u3044\u3066\u306f\u3001\u9280\u306eSAM\u96fb\u6975(FDT\/HDT=3\/1)\u304c\u91d1\u96fb\u6975\u3088\u308a\u3082\u512a\u308c\u305f\u7279\u6027\u3092\u793a\u3057\u3001\u30b2\u30fc\u30c8\u96fb\u5727\u304c-80V\u3067\u98fd\u548c\u30c9\u30ec\u30a4\u30f3\u96fb\u6d41\u304c-135\u03bcA\u3068\u91d1\u96fb\u6975\u306e2\u500d\u306e\u5024\u3092\u793a\u3059\u3053\u3068\u304c\u308f\u304b\u3063\u305f\u3002\u3055\u3089\u306b\u3001\u96fb\u8377\u79fb\u52d5\u5ea6\u304c0.21cm2\/Vs\u3067\u3001\u307b\u3068\u3093\u3069\u306e\u91d1\u96fb\u6975\u306e\u3053\u306e\u30bf\u30a4\u30d7\u306eOTFTs\u3088\u308a\u901f\u304b\u3063\u305f\u3002\u305d\u306e\u7406\u7531\u306f\u6b63\u5b54\u6ce8\u5165\u969c\u5bb3\u304c\u6e1b\u3058\u3089\u308c\u305f\u3053\u3068\u3068\u96fb\u6975\u4e0a\u3067\u306e\u30da\u30f3\u30bf\u30bb\u30f3\u306e\u7c92\u5b50\u304c\u6bd4\u8f03\u7684\u5927\u304d\u304f\u9023\u7d9a\u7684\u5206\u5e03\u3057\u3066\u3044\u308b\u3053\u3068\u306b\u3088\u308b\u3068\u3057\u3066\u3044\u308b\u3002
\n\"FT1\"
\n3\u3001\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30dd\u30ea\u30a8\u30fc\u30c6\u30eb\u88ab\u8986\u5c64\u3092\u6709\u3059\u308b\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30a8\u30fc\u30c6\u30eb\u30a2\u30eb\u30ad\u30eb\u30c1\u30aa\u30fc\u30eb\u304a\u3088\u3073\u30b8\u30c1\u30aa\u30fc\u30eb\u306eSAMs\u3092\u9285\u8868\u9762\u306b\u5f62\u6210\u3059\u308b\u3053\u30682)
\n\u4e0b\u56f3\u306b\u793a\u3059\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30a8\u30fc\u30c6\u30eb\u30a2\u30eb\u30ad\u30eb\u30c1\u30aa\u30fc\u30eb(RfSH)\u304a\u3088\u3073\u30b8\u30c1\u30aa\u30fc\u30eb(Rf(SH)2)\u306eSAMs\u3092\u9285\u8868\u9762\u306b\u5f62\u6210\u3055\u305b\u4e0d\u52d5\u5c64\u3092\u4f5c\u308a\u3001\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30dd\u30ea\u30a8\u30fc\u30c6\u30eb\uff08PFPE)\u3092\u52d5\u5c64\u3068\u3057\u3066\u5c0e\u5165\u3057\u305f\u3002
\n\"FT2\"
\nSAMs\u306e\u4f5c\u88fd\u306f\u3001\u9285\u30d5\u30a9\u30a4\u30eb\u3092\u7814\u78e8\u3057\u3001UV-\u30aa\u30be\u30f3\u3067\u51e6\u7406\u3059\u308b\u3002\u6b21\u3044\u3067\u3001\u30a8\u30bf\u30ce\u30fc\u30eb\u4e2d\u306b\u6d78\u6f2c\u3057\u3066\u8d85\u97f3\u6ce2\u6d17\u6d44\u3092\u884c\u3044\u3001\u7a92\u7d20\u6c17\u6d41\u4e2d\u3067\u4e7e\u71e5\u3059\u308b\u3002\u3055\u3089\u306b\u3001HClO4\u6c34\u6eb6\u6db2\u4e2d\u3067\u96fb\u6c17\u5316\u5b66\u7684\u9084\u5143\u3092\u884c\u3046\u3002\u305d\u306e\u9285\u30d5\u30a9\u30a4\u30eb\u3092RfSH\u304a\u3088\u3073Rf(SH)2\u30a8\u30bf\u30ce\u30fc\u30eb\u6eb6\u6db2\u4e2d\u306b\u6d78\u6f2c\u3057\u3066SAMs\u53cd\u5fdc\u3092\u884c\u308f\u305b\u308b\u3002\u30a8\u30bf\u30ce\u30fc\u30eb\u3067\u30ea\u30f3\u30b9\u3057\u305f\u5f8c\u3001\u7a92\u7d20\u3067\u4e7e\u71e5\u3059\u308b\u3002SAMs\u306e\u5f62\u6210\u306b\u3064\u3044\u3066\u306f\u3001XPS\u304a\u3088\u3073\u504f\u5149\u5909\u8abf\u9ad8\u611f\u5ea6\u53cd\u5c04\u6cd5(PM-IRRAS)\u3001\u3055\u3089\u306b\u306f\u6c34\u306e\u63a5\u89e6\u89d2\u306e\u6e2c\u5b9a\u3067\u78ba\u8a8d\u3057\u3066\u3044\u308b\u3002\u6c34\u306e\u63a5\u89e6\u89d2\u306b\u3064\u3044\u3066\u306f\u3001RfSH\u306e\u5834\u5408\u306f113\u5ea6\u3001Rf(SH)2\u306e\u5834\u5408\u306f99\u5ea6\u3067\u3042\u3063\u305f\u3002\u3053\u306e\u9055\u3044\u306f\u3001\u4e0a\u56f3\u306b\u793a\u3059\u672b\u7aef\u306eCF3\u57fa\u304c\u7d50\u5408\u3059\u308b\u9178\u7d20\u539f\u5b50\u3092\u96a0\u3059\u3053\u3068\u304c\u3067\u304d\u308b\u5426\u304b\u306e\u9055\u3044\u3067\u3042\u308a\u3001\u305d\u306e\u80fd\u529b\u306fRfSH\u306e\u65b9\u304cRf(SH)2\u3088\u308a\u9ad8\u3044\u3068\u3057\u3066\u3044\u3066\u3001\u305d\u306e\u3053\u3068\u306fPM-IRRAS\u306e\u30c7\u30fc\u30bf\u304b\u3089\u3082\u8a00\u3048\u308b\u3068\u3057\u3066\u3044\u308b\u3002\u307e\u305f\u3001\u96fb\u6c17\u5316\u5b66\u7684\u5b89\u5b9a\u6027\u306b\u3064\u3044\u3066\u306f\u3001\u30b5\u30a4\u30af\u30ea\u30c3\u30af\u30dc\u30eb\u30bf\u30e1\u30c8\u30ea\u30fc\u306e\u6e2c\u5b9a\u304b\u3089\u3001\u3044\u305a\u308c\u306eSAMs\u3082\u52b9\u679c\u304c\u3042\u308a\u3001Rf(SH)2\u306e\u65b9\u304cRfSH\u3088\u308a\u82e5\u5e72\u5b89\u5b9a\u3067\u3042\u308b\u3068\u3057\u3066\u3044\u308b\u3002\u3053\u306e\u4e8b\u5b9f\u306f\u3001\u9285\u306e\u9632\u9306\u52b9\u679c\u306b\u3064\u306a\u304c\u308b\u3002
\nPFPE\u306e\u51e6\u7406\u306f\u3001\u4e0a\u8a18\u306eSAMs\u5f62\u6210\u9285\u3092PFPE\u306e\u30d1\u30fc\u30d5\u30eb\u30aa\u30ed\u30dd\u30ea\u30a8\u30fc\u30c6\u30eb\u6eb6\u5a92\u4e2d\u306b\u30c7\u30a3\u30c3\u30d7\u3057\u3066\u884c\u3063\u305f\u3002\u3053\u306e\u5834\u5408\u306f\u3001\u8010\u6469\u8017\u6027\u306b\u5bc4\u4e0e\u3057\u3066\u3044\u308b\u3002<\/p>\n

4\u3001\u91d1\u4e0a\u306e\u6e05\u6d44\u306a\u30d5\u30c3\u7d20\u5316\u30c1\u30aa\u30fc\u30eb\u5358\u5206\u5b50\u5c64\u306e\u4f5c\u88fd\u3068\u305d\u306e\u78ba\u8a8d3)
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\n\"FT3\"
\n5\u3001\u304a\u308f\u308a\u306b
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\u6587\u732e
\n1) Chih-I Wu et al Organic Electronics 13(2012) 593-598
\n2) Zineb Mekhalif et al Electrochimica Acta 63(2012) 269-276
\n3) Ian R. Gentle et al Journal of Colloid and Interface Science 370(2012) 162-169<\/p>\n","protected":false},"excerpt":{"rendered":"

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