{"id":359,"date":"2011-11-14T16:01:19","date_gmt":"2011-11-14T07:01:19","guid":{"rendered":"http:\/\/ft-net.co.jp\/topic\/?p=359"},"modified":"2013-11-12T15:51:02","modified_gmt":"2013-11-12T06:51:02","slug":"%e3%80%8c%e3%83%95%e3%83%83%e7%b4%a0%e5%8c%96%e5%90%88%e7%89%a9%e3%81%ae%e9%85%b5%e7%b4%a0%e5%90%88%e6%88%90%e3%80%8d","status":"publish","type":"post","link":"https:\/\/ft-net.co.jp\/topic\/?p=359","title":{"rendered":"\u300c\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u9175\u7d20\u5408\u6210\u300d"},"content":{"rendered":"

\u6700\u65b0\u30d5\u30c3\u7d20\u95a2\u9023\u30c8\u30d4\u30c3\u30af\u30b9\u300d\u306f\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u682a\u5f0f\u4f1a\u793e\u30d5\u30a1\u30a4\u30f3\u30b1\u30df\u30ab\u30eb\u90e8\u306e\u3054\u597d\u610f\u306b\u3088\u308a\u3001\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u306eWEB\u30de\u30ac\u30b8\u30f3\u306b\u63b2\u8f09\u3055\u308c\u305f\u5185\u5bb9\u3092\u7d39\u4ecb\u3057\u3066\u3044\u307e\u3059\u3002\u3054\u611b\u9867\u306e\u307b\u3069\u3088\u308d\u3057\u304f\u304a\u9858\u3044\u3044\u305f\u3057\u307e\u3059\u3002\u5c1a\u3001WEB\u30de\u30ac\u30b8\u30f3\u306eURL\u306f\u4e0b\u8a18\u306e\u901a\u308a\u3067\u3059\u3002
\nhttp:\/\/www.daikin.co.jp\/chm\/products\/fine\/backnum\/201109\/#topic01<\/a><\/p>\n

1\u3001\u306f\u3058\u3081\u306b
\n\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u5408\u6210\u306b\u3064\u3044\u3066\u9175\u7d20\u3092\u89e6\u5a92\u3068\u3057\u3066\u4f7f\u7528\u3059\u308b\u65b9\u6cd5\u304c\u958b\u767a\u3055\u308c\u3066\u304d\u305f\u3002\u7279\u306b\u4e0d\u6589\u5408\u6210\u306b\u3064\u3044\u3066\u306f\u771f\u4fa1\u304c\u767a\u63ee\u3067\u304d\u305d\u3046\u3067\u3042\u308a\u3001\u307e\u305f\u7279\u6b8a\u306a\u30dd\u30ea\u30de\u30fc\u5408\u6210\u306b\u304a\u3044\u3066\u3082\u8208\u5473\u3042\u308b\u7814\u7a76\u304c\u306a\u3055\u308c\u3066\u3044\u308b\u306e\u3067\u7d39\u4ecb\u3057\u305f\u3044\u3002<\/span><\/div>\n
\"\"<\/div>\n
2\u3001\u4e0d\u6589\u5408\u6210<\/span><\/div>\n
gem-\u30b8\u30d5\u30eb\u30aa\u30ed\u30b7\u30af\u30ed\u30d7\u30ed\u30d1\u30f3\u304c\u6db2\u6676\u306e\u6750\u6599\u3068\u3057\u3066\u6ce8\u76ee\u3055\u308c\u3066\u304d\u305f\u304c\u3001\u4f0a\u85e4\u3089\u306f\u3001\u4e0b\u8a18\u306b\u793a\u3059\u87ba\u65cb\u72b6\u306egem-\u30b8\u30d5\u30eb\u30aa\u30ed\u30b7\u30af\u30ed\u30d7\u30ed\u30d1\u30f3\u306e\u8a98\u5c0e\u4f53\u3092\u5316\u5b66-\u9175\u7d20\u89e6\u5a92\u3092\u7528\u3044\u3066\u5408\u6210\u3057\u305f\u30021)<\/sup><\/span><\/div>\n
Cyclohexane-1,4-dion\u3092\u51fa\u767a\u7269\u8cc7\u3068\u3057\u3066\u3001\uff12\u3064\u306e\u30b8\u30d5\u30eb\u30aa\u30ed\u30d7\u30ed\u30d1\u30f3\u74b0\u3092\u30b7\u30af\u30ed\u30d8\u30ad\u30b5\u30f3\u3067\u7e4b\u3050\u69cb\u9020\uff11\u3092\u5316\u5b66\u89e6\u5a92\u3092\u7528\u3044\u3066\u5408\u6210\u3057\u305f\u3002\u305d\u306e\u5f8c\u3001\u4e0b\u56f3\u306b\u793a\u3059\u3088\u3046\u306b\u3001\u9175\u7d20\u89e6\u5a92Lipase\u3092\u7528\u3044\u3066\u5149\u5b66\u6d3b\u6027\u4f53\u3068\u3059\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u305f\u3002\u5404\u7a2eLipase\u3092\u7528\u3044\u305f\u5834\u5408\u306e\u5149\u5b66\u53ce\u7387\u306a\u3069\u3092Table1\u306b\u793a\u3059\u3002\u5149\u5b66\u7684\u306b\u30d4\u30e5\u30a2\u306a\u5316\u5408\u7269\u304c\u5f97\u3089\u308c\u3066\u3044\u308b\u3002<\/span><\/div>\n
\"FT1\"<\/div>\n

\u672c\u5316\u5408\u7269\u3092\u4e0b\u56f3\u306e9e\u8a98\u5c0e\u4f53\u3068\u3059\u308b\u3068\u512a\u308c\u305f\u6db2\u6676\u6027\u3092\u793a\u3059\u3053\u3068\u304c\u308f\u304b\u3063\u305f\u3002
\n\"FT2\"
\n\u5317\u722a\u3089\u306f\u3001\u30a4\u30aa\u30f3\u6db2\u4f53\u4e2d\u3067\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u4e0d\u6589\u9084\u5143\u53cd\u5fdc\u3092\u9175\u7d20\u3092\u7528\u3044\u3066\u884c\u3044\u3001\u4e0b\u8868\u306e\u7d50\u679c\u3092\u5f97\u3066\u3044\u308b\u30022)\u3053\u306e\u53cd\u5fdc\u3067\u306f\u6c34\u306e\u5b58\u5728\u304c\u91cd\u8981\u3067\u3042\u308b\u3053\u3068\u304c\u308f\u304b\u3063\u305f\u3002
\n\"FT3\"
\n3\u3001\u4f4d\u7f6e\u9078\u629e\u7684\u5408\u6210
\nSteve S.F. Yu\u3089\u306f\u3001\u4e0b\u56f3\u306b\u793a\u3059\u3088\u3046\u306agem-difluorinated octanes\u306e\u9175\u7d20\u89e6\u5a92\u306b\u3088\u308b\u4f4d\u7f6e\u9078\u629e\u7684\u30d2\u30c9\u30ed\u30ad\u30b7\u30eb\u5316\u53cd\u5fdc\u3092\u691c\u8a0e\u3057\u300111\u304c\u9078\u629e\u7684\u306b\u5408\u6210\u3055\u308c\u305f\u3053\u3068\u3092\u5831\u544a\u3057\u3066\u3044\u308b\u30023)
\n\"FT4\"
\n4\u3001\u6a5f\u80fd\u6027\u6750\u6599\u5408\u6210
\nY.Poojali\u3089\u306f\u3001\u4e0b\u56f3\u306b\u793a\u3059\u30b7\u30ea\u30b3\u30fc\u30f3\u542b\u30d5\u30c3\u7d20\u8102\u80aa\u65cf\u30dd\u30ea\u30a8\u30b9\u30c6\u30eb\u30a2\u30df\u30c9\u3092Lipase\u3092\u89e6\u5a92\u3068\u3057\u3066\u5408\u6210\u3057\u305f\u30024)
\n\"FT5\"
\nTable3\u306b\u5404\u7a2e\u7d44\u6210\u306e\u30dd\u30ea\u30de\u30fc\u306e\u5206\u5b50\u91cf\u3068\u5206\u5b50\u91cf\u5206\u5e03(PDI)\u3092\u793a\u3059\u3002
\n\"FT6\"
\n\u67d4\u8edf\u306a\u30b7\u30ea\u30b3\u30fc\u30f3\u90e8\u4f4d\u3068\u525b\u76f4\u306a\u30d5\u30eb\u30aa\u30ed\u30a2\u30eb\u30ad\u30ec\u30f3\u90e8\u4f4d\u304c\u4e3b\u9396\u306b\u4e26\u3076\u30e6\u30cb\u30fc\u30af\u306a\u30dd\u30ea\u30de\u30fc\u3067OFOD\u306e\u7d50\u6676\u6027\u306e\u767d\u8272\u56fa\u4f53\u304b\u3089APDMS\u306e\u5897\u52a0\u3068\u3068\u3082\u306b\u30a2\u30e2\u30eb\u30d5\u30a1\u30b9\u6027\u304c\u5897\u5927\u3057\u3001\u7c98\u6027\u6db2\u4f53\u304b\u3089\u30ef\u30c3\u30af\u30b9\u4f53\u306b\u5909\u5316\u3057\u305f\u3002
\nDebuigne\u3089\u306f\u3001\u4e0b\u56f3\u306b\u793a\u3059\u3001\u7cd6\u3068\u30d5\u30c3\u7d20\u542b\u6709\u30ab\u30eb\u30dc\u30f3\u9178\u3068\u3092Lipase\u3092\u89e6\u5a92\u3068\u3057\u3066\u53cd\u5fdc\u3055\u305b\u754c\u9762\u6d3b\u6027\u5264\u3092\u5408\u6210\u3057\u305f\u3002\u3053\u3053\u3067\u3001CALB\u306fCandida antarctica lipase\u3067\u3042\u308b\u3002\u53cd\u5fdc\u306f80\u210324\u6642\u9593\u306740%\u7a0b\u5ea6\u306e\u8ee2\u5316\u7387\u3067\u3042\u3063\u305f\u3002\u754c\u9762\u6d3b\u6027\u80fd\u306b\u3064\u3044\u3066\u306fFigure1\u306b\u793a\u3059\u3002\u4f4e\u3044\u8868\u9762\u5f35\u529b\u3068\u81e8\u754c\u30df\u30bb\u30eb\u6fc3\u5ea6cmc\u304c\u5f97\u3089\u308c\u3066\u3044\u308b\u3002
\n\"FT7\"
\n5\u3001\u304a\u308f\u308a\u306b
\n\u9175\u7d20\u3092\u89e6\u5a92\u3068\u3057\u3066\u7528\u3044\u305f\u30d5\u30c3\u7d20\u5316\u5408\u7269\u306e\u5408\u6210\u306f\u3001\u6e29\u548c\u306a\u6761\u4ef6\u3067\u306e\u5149\u5b66\u3042\u308b\u3044\u306f\u7acb\u4f53\u9078\u629e\u6027\u306e\u9ad8\u3044\u5316\u5408\u7269\u3084\u30e6\u30cb\u30fc\u30af\u306a\u6a5f\u80fd\u6750\u6599\u306e\u5275\u51fa\u306a\u3069\u306e\u53ef\u80fd\u6027\u304c\u3042\u308b\u3053\u3068\u304c\u5206\u304b\u3063\u305f\u3002\u4eca\u5f8c\u3001\u91cd\u8981\u306a\u5206\u91ce\u306b\u767a\u5c55\u3057\u3066\u3044\u304f\u3053\u3068\u304c\u671f\u5f85\u3055\u308c\u308b\u3002<\/p>\n

\u6587\u732e
\n1) Toshiyuki Itoh et al Journal of Fluorine Chemistry 130(2009) 1157
\n2) Tomoya Kitazume et al Tetrahedron Letters 47(2006) 4619
\n3) Steve S.F. et al Tetrahedron Letters 52(2011) 2950
\n4) Yadagiri Poojari et al Polymer 51(2010) 6161
\n5) Antonie Debuigne et al Carbohydrate Research 346(2011)\u30001161<\/p>\n

\u767a\u884c\uff1a\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u682a\u5f0f\u4f1a\u793e\u3000\u5316\u5b66\u4e8b\u696d\u90e8\u3000\u30d5\u30a1\u30a4\u30f3\u30b1\u30df\u30ab\u30eb\u90e8 WEB\u30de\u30ac\u30b8\u30f3\u4e8b\u52d9\u5c40 <\/p>\n","protected":false},"excerpt":{"rendered":"

\u6700\u65b0\u30d5\u30c3\u7d20\u95a2\u9023\u30c8\u30d4\u30c3\u30af\u30b9\u300d\u306f\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u682a\u5f0f\u4f1a\u793e\u30d5\u30a1\u30a4\u30f3\u30b1\u30df\u30ab\u30eb\u90e8\u306e\u3054\u597d\u610f\u306b\u3088\u308a\u3001\u30c0\u30a4\u30ad\u30f3\u5de5\u696d\u30db\u30fc\u30e0\u30da\u30fc\u30b8\u306eWEB\u30de\u30ac\u30b8\u30f3\u306b\u63b2\u8f09\u3055\u308c\u305f\u5185\u5bb9\u3092\u7d39\u4ecb\u3057\u3066\u3044\u307e\u3059\u3002\u3054\u611b\u9867\u306e\u307b\u3069\u3088\u308d\u3057\u304f\u304a\u9858\u3044\u3044\u305f\u3057\u307e\u3059\u3002\u5c1a\u3001WEB\u30de\u30ac\u30b8\u30f3\u306eURL … \u7d9a\u304d\u3092\u8aad\u3080<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"class_list":["post-359","post","type-post","status-publish","format-standard","hentry","category-1"],"_links":{"self":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts\/359","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=359"}],"version-history":[{"count":2,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts\/359\/revisions"}],"predecessor-version":[{"id":584,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=\/wp\/v2\/posts\/359\/revisions\/584"}],"wp:attachment":[{"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=359"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=359"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ft-net.co.jp\/topic\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=359"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}